Structure-controlled optical thermoresponse in Ruddlesden-Popper layered perovskites

Structure-controlled optical thermoresponse in Ruddlesden-Popper layered perovskites

Ruddlesden-Popper perovskites are highly attractive for light-emitting and photonic applications. In these exceptionally deformable frameworks, structural properties strongly impact on the energetic landscape of the material; thus, it is crucial to establish a correlation between the structure and o...

Full description

Saved in:
Bibliographic Details
Main Authors: Cortecchia, Daniele, Salim, Teddy, Bruno, Annalisa, Lam, Yeng Ming, Soci, Cesare, Neutzner, S., Yin, J., Srimath Kandada, A. R., Martí-Rujas, J., Petrozza, A.
Other Authors: School of Materials Science and Engineering
Format: Article
Language:English
Published: 2018
Subjects:
Perovskites
DRNTU::Science::Physics
Optical Thermoresponse
Online Access:https://hdl.handle.net/10356/89201
http://hdl.handle.net/10220/47029
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Nanyang Technological University
Language: English
Description
Summary:Ruddlesden-Popper perovskites are highly attractive for light-emitting and photonic applications. In these exceptionally deformable frameworks, structural properties strongly impact on the energetic landscape of the material; thus, it is crucial to establish a correlation between the structure and optoelectronic characteristics. Here, we study the structural transformations induced by phase transitions in the butylammonium-based series (BA)2(MA)n−1[PbnI3n+1] (n = 1 and n = 2). We show how thermally driven lattice contraction and changes in crystal packing affect their characteristic absorption and photoluminescence. These findings provide new insights for functional perovskites’ rational design, highlighting the possibility to tune the structural properties through external stimuli to control their functionalities on-demand.

Similar Items