Stibine-protected Au 13 nanoclusters : syntheses, properties and facile conversion to GSH-protected Au 25 nanocluster

Stibine-protected Au 13 nanoclusters : syntheses, properties and facile conversion to GSH-protected Au 25 nanocluster

Monostibine-protected ionic Au13 nanoclusters, namely, [Au13(L)8(Cl)4][Cl] (L= SbPh3, 2a·Cl; Sb(p-tolyl)3, 2b·Cl) were prepared by the direct reduction of Au(L)Cl with NaBH4 in dichloromethane. Anion exchange with 2a·Cl afforded [Au13(SbPh3)8(Cl)4][X] (X = PF6, 2a·PF6; BPh4, 2a·BPh4). All these have...

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Bibliographic Details
Main Authors: Li, Ying-Zhou, Ganguly, Rakesh, Hong, Kar Yiu, Li, Yongxin, Tessensohn, Malcolm Eugene, Webster, Richard, Leong, Weng Kee
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2019
Subjects:
DRNTU::Science::Chemistry
Diphosphine
Stibine-protected Au13
Online Access:https://hdl.handle.net/10356/89306
http://hdl.handle.net/10220/47696
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/89306
http://hdl.handle.net/10220/47696

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