Stibine-protected Au 13 nanoclusters : syntheses, properties and facile conversion to GSH-protected Au 25 nanocluster
Monostibine-protected ionic Au13 nanoclusters, namely, [Au13(L)8(Cl)4][Cl] (L= SbPh3, 2a·Cl; Sb(p-tolyl)3, 2b·Cl) were prepared by the direct reduction of Au(L)Cl with NaBH4 in dichloromethane. Anion exchange with 2a·Cl afforded [Au13(SbPh3)8(Cl)4][X] (X = PF6, 2a·PF6; BPh4, 2a·BPh4). All these have...
Saved in:
Main Authors: | , , , , , , |
---|---|
Other Authors: | |
Format: | Article |
Language: | English |
Published: |
2019
|
Subjects: | |
Online Access: | https://hdl.handle.net/10356/89306 http://hdl.handle.net/10220/47696 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Institution: | Nanyang Technological University |
Language: | English |
id |
sg-ntu-dr.10356-89306 |
---|---|
record_format |
dspace |
spelling |
sg-ntu-dr.10356-893062023-02-28T19:36:05Z Stibine-protected Au 13 nanoclusters : syntheses, properties and facile conversion to GSH-protected Au 25 nanocluster Li, Ying-Zhou Ganguly, Rakesh Hong, Kar Yiu Li, Yongxin Tessensohn, Malcolm Eugene Webster, Richard Leong, Weng Kee School of Physical and Mathematical Sciences DRNTU::Science::Chemistry Diphosphine Stibine-protected Au13 Monostibine-protected ionic Au13 nanoclusters, namely, [Au13(L)8(Cl)4][Cl] (L= SbPh3, 2a·Cl; Sb(p-tolyl)3, 2b·Cl) were prepared by the direct reduction of Au(L)Cl with NaBH4 in dichloromethane. Anion exchange with 2a·Cl afforded [Au13(SbPh3)8(Cl)4][X] (X = PF6, 2a·PF6; BPh4, 2a·BPh4). All these have been characterized by multinuclear NMR, ESI-MS and UV-Vis spectroscopy. Crystallographic analysis of 2a·BPh4 reveals that the cation possesses C2v symmetry and the tridecagold core adopts a closed icosahedron configuration. The weaker coordinating ability of the stibine ligands leads to the ready reaction of 2b·Cl with PPh3 or glutathione (GSH) to form the smaller phosphine-protected cluster [Au11(PPh3)8Cl2][Cl] or larger thiolate-protected cluster Au25(SG)18, respectively. In the latter reaction, the addition of a small amount (0.5 to 3.5 equivalents) of a suitable oxidant such as K3(Fe(CN)6 accelerates the conversion rate significantly. ASTAR (Agency for Sci., Tech. and Research, S’pore) Published version 2019-02-18T08:12:37Z 2019-12-06T17:22:29Z 2019-02-18T08:12:37Z 2019-12-06T17:22:29Z 2018 Journal Article Li, Y.-Z., Ganguly, R., Hong, K. Y., Li, Y., Tessensohn, M. E., Webster, R., & Leong, W. K. (2018). Stibine-protected Au13 nanoclusters: syntheses, properties and facile conversion to GSH-protected Au25 nanocluster. Chemical Science, 9(46), 8723-8730. doi:10.1039/C8SC03132K 2041-6520 https://hdl.handle.net/10356/89306 http://hdl.handle.net/10220/47696 10.1039/C8SC03132K en Chemical Science © 2018 The Author(s) (published by Royal Society of Chemistry). This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. 8 p. application/pdf |
institution |
Nanyang Technological University |
building |
NTU Library |
continent |
Asia |
country |
Singapore Singapore |
content_provider |
NTU Library |
collection |
DR-NTU |
language |
English |
topic |
DRNTU::Science::Chemistry Diphosphine Stibine-protected Au13 |
spellingShingle |
DRNTU::Science::Chemistry Diphosphine Stibine-protected Au13 Li, Ying-Zhou Ganguly, Rakesh Hong, Kar Yiu Li, Yongxin Tessensohn, Malcolm Eugene Webster, Richard Leong, Weng Kee Stibine-protected Au 13 nanoclusters : syntheses, properties and facile conversion to GSH-protected Au 25 nanocluster |
description |
Monostibine-protected ionic Au13 nanoclusters, namely, [Au13(L)8(Cl)4][Cl] (L= SbPh3, 2a·Cl; Sb(p-tolyl)3, 2b·Cl) were prepared by the direct reduction of Au(L)Cl with NaBH4 in dichloromethane. Anion exchange with 2a·Cl afforded [Au13(SbPh3)8(Cl)4][X] (X = PF6, 2a·PF6; BPh4, 2a·BPh4). All these have been characterized by multinuclear NMR, ESI-MS and UV-Vis spectroscopy. Crystallographic analysis of 2a·BPh4 reveals that the cation possesses C2v symmetry and the tridecagold core adopts a closed icosahedron configuration. The weaker coordinating ability of the stibine ligands leads to the ready reaction of 2b·Cl with PPh3 or glutathione (GSH) to form the smaller phosphine-protected cluster [Au11(PPh3)8Cl2][Cl] or larger thiolate-protected cluster Au25(SG)18, respectively. In the latter reaction, the addition of a small amount (0.5 to 3.5 equivalents) of a suitable oxidant such as K3(Fe(CN)6 accelerates the conversion rate significantly. |
author2 |
School of Physical and Mathematical Sciences |
author_facet |
School of Physical and Mathematical Sciences Li, Ying-Zhou Ganguly, Rakesh Hong, Kar Yiu Li, Yongxin Tessensohn, Malcolm Eugene Webster, Richard Leong, Weng Kee |
format |
Article |
author |
Li, Ying-Zhou Ganguly, Rakesh Hong, Kar Yiu Li, Yongxin Tessensohn, Malcolm Eugene Webster, Richard Leong, Weng Kee |
author_sort |
Li, Ying-Zhou |
title |
Stibine-protected Au 13 nanoclusters : syntheses, properties and facile conversion to GSH-protected Au 25 nanocluster |
title_short |
Stibine-protected Au 13 nanoclusters : syntheses, properties and facile conversion to GSH-protected Au 25 nanocluster |
title_full |
Stibine-protected Au 13 nanoclusters : syntheses, properties and facile conversion to GSH-protected Au 25 nanocluster |
title_fullStr |
Stibine-protected Au 13 nanoclusters : syntheses, properties and facile conversion to GSH-protected Au 25 nanocluster |
title_full_unstemmed |
Stibine-protected Au 13 nanoclusters : syntheses, properties and facile conversion to GSH-protected Au 25 nanocluster |
title_sort |
stibine-protected au 13 nanoclusters : syntheses, properties and facile conversion to gsh-protected au 25 nanocluster |
publishDate |
2019 |
url |
https://hdl.handle.net/10356/89306 http://hdl.handle.net/10220/47696 |
_version_ |
1759855008189251584 |