Asymmetric Conjugate Addition of Organoboron Reagents to Common Enones Using Copper Catalysts
Copper complexes of phosphoramidites efficiently catalyzed asymmetric addition of arylboron reagents to acyclic enones. Importantly, rare 1,4-insertion of arylcopper(I) was identified which led directly to O-bound copper enolates. The new mechanism is fundamentally different from classical oxidative...
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| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2018
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/89360 http://hdl.handle.net/10220/44890 |
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| Institution: | Nanyang Technological University |
| Language: | English |