Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation

• Main Authors: Zong, Lili, Wang, Chao, Moeljadi, Adhitya Mangala Putra, Ye, Xinyi, Ganguly, Rakesh, Li, Yongxin, Hirao, Hajime, Tan, Choon-Hong
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2018
• Subjects: Catalytic Mechanisms; Asymmetric Catalysis; DRNTU::Science::Physics
• Online Access: https://hdl.handle.net/10356/89822; http://hdl.handle.net/10220/47160
• Institution: Nanyang Technological University

Catalytic use of peroxomolybdate for asymmetric transformations has attracted increasing attention due to its catalytic properties and application in catalysis. Herein, we report chiral bisguanidinium dinuclear oxodiperoxomolybdosulfate [BG]2+[(μ-SO4)Mo2O2(μ-O2)2(O2)2]2− ion pair, as a catalyst for...