Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation

• Main Authors: Zong, Lili, Wang, Chao, Moeljadi, Adhitya Mangala Putra, Ye, Xinyi, Ganguly, Rakesh, Li, Yongxin, Hirao, Hajime, Tan, Choon-Hong
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2018
• 主題: Catalytic Mechanisms; Asymmetric Catalysis; DRNTU::Science::Physics
• 在線閱讀: https://hdl.handle.net/10356/89822; http://hdl.handle.net/10220/47160
• 機構: Nanyang Technological University

Catalytic use of peroxomolybdate for asymmetric transformations has attracted increasing attention due to its catalytic properties and application in catalysis. Herein, we report chiral bisguanidinium dinuclear oxodiperoxomolybdosulfate [BG]2+[(μ-SO4)Mo2O2(μ-O2)2(O2)2]2− ion pair, as a catalyst for...