A light-stimulated molecular switch driven by radical–radical interactions in water
A redox-controllable bistable [2]rotaxane has been synthesized using templation and click chemistry. With assistance from a sacrificial electron donor, light-triggered switching through numerous cycles can be initiated by radical-pairing interactions between the reduced forms of the cyclophane and t...
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| Main Authors: | , , , , , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2012
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/90515 http://hdl.handle.net/10220/7456 |
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| Institution: | Nanyang Technological University |
| Language: | English |