Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers
An efficient rhodium-catalyzed synthesis of 2H-azirines and pyrroles has been developed. Novel rearrangement of α-oximino ketenes derived from α-diazo oxime ethers provides 2H-azirines bearing quaternary centers and allows for subsequent rearrangement to highly substituted pyrroles in excellent yiel...
Saved in:
| Main Authors: | , , |
|---|---|
| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2013
|
| Online Access: | https://hdl.handle.net/10356/95800 http://hdl.handle.net/10220/11202 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Institution: | Nanyang Technological University |
| Language: | English |
| id |
sg-ntu-dr.10356-95800 |
|---|---|
| record_format |
dspace |
| spelling |
sg-ntu-dr.10356-958002020-03-07T12:37:21Z Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers Jiang, Yaojia Chan, Wei Chuen Park, Cheol-Min School of Physical and Mathematical Sciences An efficient rhodium-catalyzed synthesis of 2H-azirines and pyrroles has been developed. Novel rearrangement of α-oximino ketenes derived from α-diazo oxime ethers provides 2H-azirines bearing quaternary centers and allows for subsequent rearrangement to highly substituted pyrroles in excellent yields. 2013-07-11T06:06:58Z 2019-12-06T19:21:48Z 2013-07-11T06:06:58Z 2019-12-06T19:21:48Z 2012 2012 Journal Article Jiang, Y., Chan, W. C., & Park, C. M. (2012). Expedient Synthesis of Highly Substituted Pyrroles via Tandem Rearrangement of α-Diazo Oxime Ethers. Journal of the American Chemical Society, 134(9), 4104-4107. https://hdl.handle.net/10356/95800 http://hdl.handle.net/10220/11202 10.1021/ja300552c en Journal of the American chemical society © 2012 American Chemical Society. |
| institution |
Nanyang Technological University |
| building |
NTU Library |
| country |
Singapore |
| collection |
DR-NTU |
| language |
English |
| description |
An efficient rhodium-catalyzed synthesis of 2H-azirines and pyrroles has been developed. Novel rearrangement of α-oximino ketenes derived from α-diazo oxime ethers provides 2H-azirines bearing quaternary centers and allows for subsequent rearrangement to highly substituted pyrroles in excellent yields. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Jiang, Yaojia Chan, Wei Chuen Park, Cheol-Min |
| format |
Article |
| author |
Jiang, Yaojia Chan, Wei Chuen Park, Cheol-Min |
| spellingShingle |
Jiang, Yaojia Chan, Wei Chuen Park, Cheol-Min Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers |
| author_sort |
Jiang, Yaojia |
| title |
Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers |
| title_short |
Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers |
| title_full |
Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers |
| title_fullStr |
Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers |
| title_full_unstemmed |
Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers |
| title_sort |
expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers |
| publishDate |
2013 |
| url |
https://hdl.handle.net/10356/95800 http://hdl.handle.net/10220/11202 |
| _version_ |
1681046948215259136 |