Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers
An efficient rhodium-catalyzed synthesis of 2H-azirines and pyrroles has been developed. Novel rearrangement of α-oximino ketenes derived from α-diazo oxime ethers provides 2H-azirines bearing quaternary centers and allows for subsequent rearrangement to highly substituted pyrroles in excellent yiel...
Saved in:
Main Authors: | , , |
---|---|
Other Authors: | |
Format: | Article |
Language: | English |
Published: |
2013
|
Online Access: | https://hdl.handle.net/10356/95800 http://hdl.handle.net/10220/11202 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Institution: | Nanyang Technological University |
Language: | English |
id |
sg-ntu-dr.10356-95800 |
---|---|
record_format |
dspace |
spelling |
sg-ntu-dr.10356-958002020-03-07T12:37:21Z Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers Jiang, Yaojia Chan, Wei Chuen Park, Cheol-Min School of Physical and Mathematical Sciences An efficient rhodium-catalyzed synthesis of 2H-azirines and pyrroles has been developed. Novel rearrangement of α-oximino ketenes derived from α-diazo oxime ethers provides 2H-azirines bearing quaternary centers and allows for subsequent rearrangement to highly substituted pyrroles in excellent yields. 2013-07-11T06:06:58Z 2019-12-06T19:21:48Z 2013-07-11T06:06:58Z 2019-12-06T19:21:48Z 2012 2012 Journal Article Jiang, Y., Chan, W. C., & Park, C. M. (2012). Expedient Synthesis of Highly Substituted Pyrroles via Tandem Rearrangement of α-Diazo Oxime Ethers. Journal of the American Chemical Society, 134(9), 4104-4107. https://hdl.handle.net/10356/95800 http://hdl.handle.net/10220/11202 10.1021/ja300552c en Journal of the American chemical society © 2012 American Chemical Society. |
institution |
Nanyang Technological University |
building |
NTU Library |
country |
Singapore |
collection |
DR-NTU |
language |
English |
description |
An efficient rhodium-catalyzed synthesis of 2H-azirines and pyrroles has been developed. Novel rearrangement of α-oximino ketenes derived from α-diazo oxime ethers provides 2H-azirines bearing quaternary centers and allows for subsequent rearrangement to highly substituted pyrroles in excellent yields. |
author2 |
School of Physical and Mathematical Sciences |
author_facet |
School of Physical and Mathematical Sciences Jiang, Yaojia Chan, Wei Chuen Park, Cheol-Min |
format |
Article |
author |
Jiang, Yaojia Chan, Wei Chuen Park, Cheol-Min |
spellingShingle |
Jiang, Yaojia Chan, Wei Chuen Park, Cheol-Min Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers |
author_sort |
Jiang, Yaojia |
title |
Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers |
title_short |
Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers |
title_full |
Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers |
title_fullStr |
Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers |
title_full_unstemmed |
Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers |
title_sort |
expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers |
publishDate |
2013 |
url |
https://hdl.handle.net/10356/95800 http://hdl.handle.net/10220/11202 |
_version_ |
1681046948215259136 |