Cu(II)-mediated aminooxygenation of alkenylimines and alkenylamidines with TEMPO

Cu(II)-mediated aminooxygenation of alkenylimines and alkenylamidines with TEMPO

A method for the synthesis of oxymethyl dihydropyrroles (pyrrolines) and dihydroimidazoles has been developed via Cu(II)-mediated intramolecular aminooxygenation of alkenylim­ines and alkenylamidines, respectively, with 2,2,6,6-tetramethyl-1-piperidinyloxy radical (TEMPO).

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Bibliographic Details
Main Authors: Sanjaya, Stephen, Chua, Sze Hui, Chiba, Shunsuke
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/96256
http://hdl.handle.net/10220/11889
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Institution: Nanyang Technological University
Language: English
Description
Summary:A method for the synthesis of oxymethyl dihydropyrroles (pyrrolines) and dihydroimidazoles has been developed via Cu(II)-mediated intramolecular aminooxygenation of alkenylim­ines and alkenylamidines, respectively, with 2,2,6,6-tetramethyl-1-piperidinyloxy radical (TEMPO).

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