Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride

Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride

In the presence of copper(I) chloride, tert-butyl 1-hydroxy-2-methyl-6-trifluoromethyl-1H-indole-3-carboxylate acted as a catalyst for the chemoselective aerobic oxidation of allylic and benzylic alcohols. A variety of primary and secondary allylic and benzylic alcohols were oxidized into the corres...

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Main Authors: Shen, Shu-Su, Kartika, Vita, Tan, Ying Shan, Webster, Richard David, Narasaka, Koichi
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/96586
http://hdl.handle.net/10220/10308
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-965862020-03-07T12:34:43Z Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride Shen, Shu-Su Kartika, Vita Tan, Ying Shan Webster, Richard David Narasaka, Koichi School of Physical and Mathematical Sciences In the presence of copper(I) chloride, tert-butyl 1-hydroxy-2-methyl-6-trifluoromethyl-1H-indole-3-carboxylate acted as a catalyst for the chemoselective aerobic oxidation of allylic and benzylic alcohols. A variety of primary and secondary allylic and benzylic alcohols were oxidized into the corresponding α,β-unsaturated carbonyl compounds in good yields without affecting non-allylic alcohols. 2013-06-13T03:23:09Z 2019-12-06T19:32:47Z 2013-06-13T03:23:09Z 2019-12-06T19:32:47Z 2011 2011 Journal Article Shen, S.-S., Kartika, V., Tan, Y. S., Webster, R. D., & Narasaka, K. (2012). Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride. Tetrahedron Letters, 53(8), 986-990. 0040-4039 https://hdl.handle.net/10356/96586 http://hdl.handle.net/10220/10308 10.1016/j.tetlet.2011.12.058 en Tetrahedron letters © 2011 Elsevier Ltd.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
description In the presence of copper(I) chloride, tert-butyl 1-hydroxy-2-methyl-6-trifluoromethyl-1H-indole-3-carboxylate acted as a catalyst for the chemoselective aerobic oxidation of allylic and benzylic alcohols. A variety of primary and secondary allylic and benzylic alcohols were oxidized into the corresponding α,β-unsaturated carbonyl compounds in good yields without affecting non-allylic alcohols.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Shen, Shu-Su
Kartika, Vita
Tan, Ying Shan
Webster, Richard David
Narasaka, Koichi
format Article
author Shen, Shu-Su
Kartika, Vita
Tan, Ying Shan
Webster, Richard David
Narasaka, Koichi
spellingShingle Shen, Shu-Su
Kartika, Vita
Tan, Ying Shan
Webster, Richard David
Narasaka, Koichi
Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride
author_sort Shen, Shu-Su
title Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride
title_short Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride
title_full Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride
title_fullStr Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride
title_full_unstemmed Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride
title_sort selective aerobic oxidation of allylic and benzylic alcohols catalyzed by n-hydroxyindole and copper(i) chloride
publishDate 2013
url https://hdl.handle.net/10356/96586
http://hdl.handle.net/10220/10308
_version_ 1681034105519603712

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