Scandium as a pre-catalyst for the deoxygenative allylation of benzylic alcohols

Scandium as a pre-catalyst for the deoxygenative allylation of benzylic alcohols

Scandium triflate is an effective pre-catalyst for the deoxygenative allylation of benzylic alcohols with a narrow substrate window. The reaction is shown to proceed through a “hidden Brønsted acid” mechanism. The reaction is efficient provided that the aryl group is neither too electron rich nor to...

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Bibliographic Details
Main Authors: Šolić, Ivan, Seankongsuk, Pattarakiat, Loh, Joanna Kejun, Vilaivan, Tirayut, Bates, Roderick Wayland
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2019
Subjects:
DRNTU::Science::Chemistry
Allylation
Benzylic Alcohols
Online Access:https://hdl.handle.net/10356/90299
http://hdl.handle.net/10220/48477
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/90299
http://hdl.handle.net/10220/48477

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