Reactivity of digermylenes toward potassium graphite : synthesis and characterization of germylidenide anions

• المؤلفون الرئيسيون: Chia, Siew-Peng, Yeong, Hui-Xian, So, Cheuk-Wai
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2013
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/96788; http://hdl.handle.net/10220/11595
• المؤسسة: Nanyang Technological University

The synthesis and characterization of the digermylenes [LGe–GeL] [L = L1 (3A), L2 (3B)] supported by the 2,6-diiminophenyl (L1) and 2-imino-5,6-methylenedioxylphenyl (L2) ligands are described. Their reactivities toward potassium graphite are also reported. The reaction of [LGeCl] [L = L1 (2A), L2 (...