One-pot synthesis of carbon-coated VO2(B) nanobelts for high-rate lithium storage

• Main Authors: Lim, Tuti Mariana, Rui, Xianhong, Sim, Daohao, Xu, Chen, Liu, Weiling, Tan, Huiteng, Wong, Kangming, Hng, Huey Hoon, Yan, Qingyu
• Other Authors: School of Civil and Environmental Engineering
• Format: Article
• Language: English
• Published: 2013
• Online Access: https://hdl.handle.net/10356/97133; http://hdl.handle.net/10220/10410
• Institution: Nanyang Technological University

Uniform carbon-coated single crystalline vanadium dioxide (VO2(B)@C) nanobelts were successfully prepared by using a facile one-pot hydrothermal approach. Sucrose plays a dual role in this hydrothermal process, namely as a carbon precursor for the carbon shell and, as a reductant to reduce V2O5 to VO2(B). The thickness of the carbon coating layer is tunable from 3.0 to 6.9 nm by changing the ratio of the precursors. Although a high carbon content can improve the electrical conductivity of VO2(B)@C nanobelts, a thick carbon coating layer would block the lithium ion diffusion. The optimal thickness is found to be 4.3 nm (carbon content: 6.6 wt%), where the cathode displays superior performance with highly reversible specific capacities, good cycling stabilities and excellent rate capabilities (e.g. 100 mA h g−1 at 12.4 C).