Palladacycle-catalyzed tandem allylic amination/allylation protocol for one-pot synthesis of 2-allylanilines from allylic alcohols

An efficient methodology involving the predominant formation of CC bonds is described for the first direct synthesis of 2-allylanilines from allylic alcohols via a one-pot tandem allylic amination/allylation protocol catalyzed by a palladacycle under mild conditions without the requirement for addit...

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Bibliographic Details
Main Authors: Chen, Ke, Li, Yongxin, Pullarkat, Sumod A., Leung, Pak-Hing
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/98294
http://hdl.handle.net/10220/12331
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Institution: Nanyang Technological University
Language: English
Description
Summary:An efficient methodology involving the predominant formation of CC bonds is described for the first direct synthesis of 2-allylanilines from allylic alcohols via a one-pot tandem allylic amination/allylation protocol catalyzed by a palladacycle under mild conditions without the requirement for additional activators.