Palladium-catalyzed direct C-H arylation of enamides with simple arenes

• المؤلفون الرئيسيون: Pankajakshan, Sreekumar, Xu, Yun-He, Cheng, Jun Kee, Low, Man Ting, Loh, Teck-Peng
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2013
• الموضوعات: DRNTU::Science::Chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/98400; http://hdl.handle.net/10220/12496
• المؤسسة: Nanyang Technological University

Z only: An atom-economical synthetic route towards arylated Z-enamides through double CH functionalization is described. The Z/E selectivity of the palladium-catalyzed monoarylation is absolute (step A in scheme), and the molecular complexity of the products can be further endowed by a sequential se...