Synthesis of 3-Oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester
Cascades: An InBr3-catalyzed intermolecular polyene cyclization initiated by a Prins reaction provides a concise approach to 3-oxaterpenoid derivatives. The reaction is compatible with various aldehydes, ketones, and polyolefin–alcohol substrates. In addition, the total synthesis of (±)-moluccanic a...
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sg-ntu-dr.10356-984552020-03-07T12:34:47Z Synthesis of 3-Oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester Li, Bin Lai, Yin-Chang Zhao, Yujun Wong, Yiu-Hang Shen, Zhi-Liang Loh, Teck-Peng School of Physical and Mathematical Sciences DRNTU::Science::Chemistry Cascades: An InBr3-catalyzed intermolecular polyene cyclization initiated by a Prins reaction provides a concise approach to 3-oxaterpenoid derivatives. The reaction is compatible with various aldehydes, ketones, and polyolefin–alcohol substrates. In addition, the total synthesis of (±)-moluccanic acid methyl ester was achieved in seven steps by using such a Prins–polyene cyclization as the key step. 2013-07-29T07:21:19Z 2019-12-06T19:55:24Z 2013-07-29T07:21:19Z 2019-12-06T19:55:24Z 2012 2012 Journal Article Li, B., Lai, Y.-C., Zhao, Y., Wong, Y.-H., Shen, Z.-L., & Loh, T.-P. (2012). Synthesis of 3-Oxaterpenoids and Its Application in the Total Synthesis of (±)-Moluccanic Acid Methyl Ester. Angewandte Chemie International Edition, 51(42), 10619-10623. 1433-7851 https://hdl.handle.net/10356/98455 http://hdl.handle.net/10220/12483 10.1002/anie.201205981 en Angewandte chemie international edition © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
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DRNTU::Science::Chemistry Li, Bin Lai, Yin-Chang Zhao, Yujun Wong, Yiu-Hang Shen, Zhi-Liang Loh, Teck-Peng Synthesis of 3-Oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester |
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Cascades: An InBr3-catalyzed intermolecular polyene cyclization initiated by a Prins reaction provides a concise approach to 3-oxaterpenoid derivatives. The reaction is compatible with various aldehydes, ketones, and polyolefin–alcohol substrates. In addition, the total synthesis of (±)-moluccanic acid methyl ester was achieved in seven steps by using such a Prins–polyene cyclization as the key step. |
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School of Physical and Mathematical Sciences |
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School of Physical and Mathematical Sciences Li, Bin Lai, Yin-Chang Zhao, Yujun Wong, Yiu-Hang Shen, Zhi-Liang Loh, Teck-Peng |
| format |
Article |
| author |
Li, Bin Lai, Yin-Chang Zhao, Yujun Wong, Yiu-Hang Shen, Zhi-Liang Loh, Teck-Peng |
| author_sort |
Li, Bin |
| title |
Synthesis of 3-Oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester |
| title_short |
Synthesis of 3-Oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester |
| title_full |
Synthesis of 3-Oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester |
| title_fullStr |
Synthesis of 3-Oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester |
| title_full_unstemmed |
Synthesis of 3-Oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester |
| title_sort |
synthesis of 3-oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester |
| publishDate |
2013 |
| url |
https://hdl.handle.net/10356/98455 http://hdl.handle.net/10220/12483 |
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1681037403668611072 |