The original coordination chemistry of 2-phosphaphenol with copper(I) and gold(I) halides

2-Phosphaphenol (L) forms unusual complexes with copper and gold halides. With CuCl, a dimeric [L2CuCl]2 complex is observed with L acting both as η1-P terminal and μ2-P bridging ligand and a copper–copper short contact of 2.549 Å. With copper bromide, a distorted infinite chain [L2CuBr]n is formed,...

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Bibliographic Details
Main Authors: Mao, Yanli, Lim, Kelvin Meng Hui, Li, Yongxin, Ganguly, Rakesh, Mathey, François
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/98671
http://hdl.handle.net/10220/17365
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Institution: Nanyang Technological University
Language: English