The original coordination chemistry of 2-phosphaphenol with copper(I) and gold(I) halides

• Main Authors: Mao, Yanli, Lim, Kelvin Meng Hui, Li, Yongxin, Ganguly, Rakesh, Mathey, François
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2013
• 在線閱讀: https://hdl.handle.net/10356/98671; http://hdl.handle.net/10220/17365

2-Phosphaphenol (L) forms unusual complexes with copper and gold halides. With CuCl, a dimeric [L2CuCl]2 complex is observed with L acting both as η1-P terminal and μ2-P bridging ligand and a copper–copper short contact of 2.549 Å. With copper bromide, a distorted infinite chain [L2CuBr]n is formed,...