Generation and reactivity of methylphosphaketene in the coordination sphere of tungsten

The [4 + 2] cycloadduct between the 1-methyl-2-keto-1,2-dihydrophosphinine pentacarbonyltungsten complex and dimethyl acetylenedicarboxylate can be used as a precursor for the methylphosphaketene tungsten complex under UV irradiation at room temperature. Under these conditions, the phosphaketene com...

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Bibliographic Details
Main Authors: Mao, Yanli, Wang, Zhiyue, Ganguly, Rakesh, Mathey, François
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Subjects:
Online Access:https://hdl.handle.net/10356/99720
http://hdl.handle.net/10220/13709
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Institution: Nanyang Technological University
Language: English