Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization

High octane: A novel and practical syntheses of 8-oxabicyclo[3.2.1]octanes using a cationic cascade cyclization reaction has been developed (see scheme; TIPS=triisopropylsilyl). The diastereomer of the cyclization product isolated depends upon whether the acetal or aldehyde substrate is used.

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Main Authors: Li, Bin, Zhao, Yu-Jun, Lai, Yin-Chang, Loh, Teck-Peng
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/99014
http://hdl.handle.net/10220/12443
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-990142020-03-07T12:34:45Z Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization Li, Bin Zhao, Yu-Jun Lai, Yin-Chang Loh, Teck-Peng School of Physical and Mathematical Sciences High octane: A novel and practical syntheses of 8-oxabicyclo[3.2.1]octanes using a cationic cascade cyclization reaction has been developed (see scheme; TIPS=triisopropylsilyl). The diastereomer of the cyclization product isolated depends upon whether the acetal or aldehyde substrate is used. 2013-07-29T04:41:17Z 2019-12-06T20:02:20Z 2013-07-29T04:41:17Z 2019-12-06T20:02:20Z 2012 2012 Journal Article Li, B., Zhao, Y.-J., Lai, Y.-C., & Loh, T.-P. (2012). Asymmetric Syntheses of 8-Oxabicyclo[3,2,1]octanes: A Cationic Cascade Cyclization. Angewandte Chemie International Edition, 51(32), 8041-8045. 1433-7851 https://hdl.handle.net/10356/99014 http://hdl.handle.net/10220/12443 10.1002/anie.201202699 en Angewandte chemie international edition © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
description High octane: A novel and practical syntheses of 8-oxabicyclo[3.2.1]octanes using a cationic cascade cyclization reaction has been developed (see scheme; TIPS=triisopropylsilyl). The diastereomer of the cyclization product isolated depends upon whether the acetal or aldehyde substrate is used.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Li, Bin
Zhao, Yu-Jun
Lai, Yin-Chang
Loh, Teck-Peng
format Article
author Li, Bin
Zhao, Yu-Jun
Lai, Yin-Chang
Loh, Teck-Peng
spellingShingle Li, Bin
Zhao, Yu-Jun
Lai, Yin-Chang
Loh, Teck-Peng
Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization
author_sort Li, Bin
title Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization
title_short Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization
title_full Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization
title_fullStr Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization
title_full_unstemmed Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization
title_sort asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization
publishDate 2013
url https://hdl.handle.net/10356/99014
http://hdl.handle.net/10220/12443
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