A new type of phosphaferrocene–pyrrole–phosphaferrocene P-N-P pincer ligand
A 2-ethoxycarbonylphosphaferrocene was reduced to the corresponding 2-hydroxymethyl derivative, which was condensed with pyrrole in a 2:1 ratio in the presence of BF3 to give a phosphaferrocene–pyrrole–phosphaferrocene pincer ligand. This tridentate ligand, in turn, reacted with [Rh(acac)(CO)2] to y...
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格式: | Article |
語言: | English |
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2013
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在線閱讀: | https://hdl.handle.net/10356/99361 http://hdl.handle.net/10220/13711 |
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