A new type of phosphaferrocene–pyrrole–phosphaferrocene P-N-P pincer ligand
A 2-ethoxycarbonylphosphaferrocene was reduced to the corresponding 2-hydroxymethyl derivative, which was condensed with pyrrole in a 2:1 ratio in the presence of BF3 to give a phosphaferrocene–pyrrole–phosphaferrocene pincer ligand. This tridentate ligand, in turn, reacted with [Rh(acac)(CO)2] to y...
Saved in:
Main Authors: | Tian, Rongqiang, Ng, Yongxiang, Ganguly, Rakesh, Mathey, François |
---|---|
Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2013
|
Subjects: | |
Online Access: | https://hdl.handle.net/10356/99361 http://hdl.handle.net/10220/13711 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Institution: | Nanyang Technological University |
Language: | English |
Similar Items
-
Activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl)
by: Ho, Feny, et al.
Published: (2014) -
Access to C-Stereogenic PN(sp²)P Pincer Ligands via Phosphapalladacycle Catalyzed Asymmetric Hydrophosphination
by: Foo, Ce Qing, et al.
Published: (2022) -
Development of PNP pincer ligands and their metal complexes via Pd(II)-catalyzed P(III)-C bond formation
by: Foo, Ce Qing
Published: (2022) -
Versatile syntheses of optically pure PCE pincer ligands : facile modifications of the pendant arms and ligand backbones
by: Pullarkat, Sumod Appukuttan, et al.
Published: (2015) -
Synthesis of stereoprojecting, chiral N-C(sp3)-E type pincer complexes
by: Balázs, László B., et al.
Published: (2020)