Degree of esterification and gelling properties of pectin structure in coffee pulp
© 2016 Trans Tech Publications, Switzerland. Pectin is a high value functional food ingredient widely used as a gelling agent and stabilizer. The chemical structure of pectin has been the subject of scientific investigations for decades. Coffee producers remove beans; the other source of pectin, fro...
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th-cmuir.6653943832-424632017-09-28T04:27:13Z Degree of esterification and gelling properties of pectin structure in coffee pulp Rakitikul W. Nimmanpipug P. © 2016 Trans Tech Publications, Switzerland. Pectin is a high value functional food ingredient widely used as a gelling agent and stabilizer. The chemical structure of pectin has been the subject of scientific investigations for decades. Coffee producers remove beans; the other source of pectin, from coffee cherries is thrown away. Our study showed that pectin extracted from coffee pulp has high degree of esterification and methoxyl content of 93.75% and 7.87 respectively, which indicated good gelation properties. Nevertheless, here we were interested in the primary structure of pectin which is a complex polysaccharides that contains 1, 4-linked α-D-galactosyluronic acid (GalpA) residue. A theoretical dimension, density functional theory (DFT) with Generalized Gradient Approximation (GGA)/BLYP functions, was utilized to study methylester substitution in pectin model compounds. For further discussion, the use of a COSMO model in different solvent showed the significant results in the difference torsion angle and HOMO diagram. 2017-09-28T04:27:13Z 2017-09-28T04:27:13Z 2016-01-01 Book Series 10139826 2-s2.0-84958175158 10.4028/www.scientific.net/KEM.675-676.11 https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84958175158&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/42463 |
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© 2016 Trans Tech Publications, Switzerland. Pectin is a high value functional food ingredient widely used as a gelling agent and stabilizer. The chemical structure of pectin has been the subject of scientific investigations for decades. Coffee producers remove beans; the other source of pectin, from coffee cherries is thrown away. Our study showed that pectin extracted from coffee pulp has high degree of esterification and methoxyl content of 93.75% and 7.87 respectively, which indicated good gelation properties. Nevertheless, here we were interested in the primary structure of pectin which is a complex polysaccharides that contains 1, 4-linked α-D-galactosyluronic acid (GalpA) residue. A theoretical dimension, density functional theory (DFT) with Generalized Gradient Approximation (GGA)/BLYP functions, was utilized to study methylester substitution in pectin model compounds. For further discussion, the use of a COSMO model in different solvent showed the significant results in the difference torsion angle and HOMO diagram. |
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Rakitikul W. Nimmanpipug P. |
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Rakitikul W. Nimmanpipug P. Degree of esterification and gelling properties of pectin structure in coffee pulp |
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Rakitikul W. Nimmanpipug P. |
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Rakitikul W. |
title |
Degree of esterification and gelling properties of pectin structure in coffee pulp |
title_short |
Degree of esterification and gelling properties of pectin structure in coffee pulp |
title_full |
Degree of esterification and gelling properties of pectin structure in coffee pulp |
title_fullStr |
Degree of esterification and gelling properties of pectin structure in coffee pulp |
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Degree of esterification and gelling properties of pectin structure in coffee pulp |
title_sort |
degree of esterification and gelling properties of pectin structure in coffee pulp |
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2017 |
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https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84958175158&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/42463 |
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