Diffuse dielectric behavior of (Bi0.5Na0.5)Zr 1-xTix O3 lead-free ceramics

(Bi0.5Na0.5)Zr1-xTixO 3 with x = 0, 0.1, 0.2, 0.3, 0.4, 0.5 and 0.6 ceramics were fabricated by a conventional sintering technique at 850-950°C for 2 h. From X-ray diffraction study, three regions of different phases were observed in the ceramic system i.e., orthorhombic phase region (0 ≤ x ≤ 0.2),...

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Bibliographic Details
Main Authors: Jaiban P., Jiansirisomboon S., Watcharapasorn A., Yimnirun R., Guo R., Bhalla A.S.
Format: Article
Language:English
Published: 2014
Online Access:http://www.scopus.com/inward/record.url?eid=2-s2.0-84892877615&partnerID=40&md5=200cfc6a0c8b16d8d28dd2bccf8f4d27
http://cmuir.cmu.ac.th/handle/6653943832/4753
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Institution: Chiang Mai University
Language: English
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Summary:(Bi0.5Na0.5)Zr1-xTixO 3 with x = 0, 0.1, 0.2, 0.3, 0.4, 0.5 and 0.6 ceramics were fabricated by a conventional sintering technique at 850-950°C for 2 h. From X-ray diffraction study, three regions of different phases were observed in the ceramic system i.e., orthorhombic phase region (0 ≤ x ≤ 0.2), mixed-phase region (0.3 ≤ x ≤ 0.4), and rhombohedral phase region (0.5 ≤ x ≤ 0.6). The observed diffuse dielectric phase transition could be correlated to the compositional inhomogeneity of the samples. The dielectric properties as a function of the temperature at different frequency indicated normal ferroelectric behavior in BNZ and BNZT ceramics. The phase transformation from orthorhombic phase to rhombohderal phase affected significantly the dielectric enhancement and decrease of the maximum temperature in this ceramic system. © 2014 Copyright Taylor and Francis Group, LLC.