Metallosurfactants: Interfaces and micelles

Incorporating a metal cation as an integral component of the headgroup of a surfactant - a metallosurfactant - offers a route to concentrate these ions and their associated functionality at interfaces. To reduce the lability of the metal, various chelating or macrocyclic ligands may be employed lead...

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Bibliographic Details
Main Authors: Griffiths P.C., Fallis I.A., Chuenpratoom T., Watanesk R.
Format: Review
Language:English
Published: 2014
Online Access:http://www.scopus.com/inward/record.url?eid=2-s2.0-33748184382&partnerID=40&md5=f6b0f39c9455f6d6ad354ffa07a19b9f
http://cmuir.cmu.ac.th/handle/6653943832/5078
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Institution: Chiang Mai University
Language: English
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Summary:Incorporating a metal cation as an integral component of the headgroup of a surfactant - a metallosurfactant - offers a route to concentrate these ions and their associated functionality at interfaces. To reduce the lability of the metal, various chelating or macrocyclic ligands may be employed leading to a family of homologous series of related metallosurfactants with a structural diversity that is arguably broader than is inherently possible with conventional surfactants. This review discusses the small number of key papers that are quantifying the physico-chemical properties of metallosurfactants and highlights their "classical" as well as "non-classical" surfactant behaviour, providing an insight into the structure of micelles and films formed from these novel materials. © 2006 Elsevier B.V. All rights reserved.