Metallosurfactants: Interfaces and micelles
Incorporating a metal cation as an integral component of the headgroup of a surfactant - a metallosurfactant - offers a route to concentrate these ions and their associated functionality at interfaces. To reduce the lability of the metal, various chelating or macrocyclic ligands may be employed lead...
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2014
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th-cmuir.6653943832-50782014-08-30T02:56:07Z Metallosurfactants: Interfaces and micelles Griffiths P.C. Fallis I.A. Chuenpratoom T. Watanesk R. Incorporating a metal cation as an integral component of the headgroup of a surfactant - a metallosurfactant - offers a route to concentrate these ions and their associated functionality at interfaces. To reduce the lability of the metal, various chelating or macrocyclic ligands may be employed leading to a family of homologous series of related metallosurfactants with a structural diversity that is arguably broader than is inherently possible with conventional surfactants. This review discusses the small number of key papers that are quantifying the physico-chemical properties of metallosurfactants and highlights their "classical" as well as "non-classical" surfactant behaviour, providing an insight into the structure of micelles and films formed from these novel materials. © 2006 Elsevier B.V. All rights reserved. 2014-08-30T02:56:07Z 2014-08-30T02:56:07Z 2006 Review 00018686 10.1016/j.cis.2006.06.010 ACISB http://www.scopus.com/inward/record.url?eid=2-s2.0-33748184382&partnerID=40&md5=f6b0f39c9455f6d6ad354ffa07a19b9f http://cmuir.cmu.ac.th/handle/6653943832/5078 English |
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Incorporating a metal cation as an integral component of the headgroup of a surfactant - a metallosurfactant - offers a route to concentrate these ions and their associated functionality at interfaces. To reduce the lability of the metal, various chelating or macrocyclic ligands may be employed leading to a family of homologous series of related metallosurfactants with a structural diversity that is arguably broader than is inherently possible with conventional surfactants. This review discusses the small number of key papers that are quantifying the physico-chemical properties of metallosurfactants and highlights their "classical" as well as "non-classical" surfactant behaviour, providing an insight into the structure of micelles and films formed from these novel materials. © 2006 Elsevier B.V. All rights reserved. |
| format |
Review |
| author |
Griffiths P.C. Fallis I.A. Chuenpratoom T. Watanesk R. |
| spellingShingle |
Griffiths P.C. Fallis I.A. Chuenpratoom T. Watanesk R. Metallosurfactants: Interfaces and micelles |
| author_facet |
Griffiths P.C. Fallis I.A. Chuenpratoom T. Watanesk R. |
| author_sort |
Griffiths P.C. |
| title |
Metallosurfactants: Interfaces and micelles |
| title_short |
Metallosurfactants: Interfaces and micelles |
| title_full |
Metallosurfactants: Interfaces and micelles |
| title_fullStr |
Metallosurfactants: Interfaces and micelles |
| title_full_unstemmed |
Metallosurfactants: Interfaces and micelles |
| title_sort |
metallosurfactants: interfaces and micelles |
| publishDate |
2014 |
| url |
http://www.scopus.com/inward/record.url?eid=2-s2.0-33748184382&partnerID=40&md5=f6b0f39c9455f6d6ad354ffa07a19b9f http://cmuir.cmu.ac.th/handle/6653943832/5078 |
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1681420357477597184 |