Redox coupled-spin crossover in cobalt β-diketonate complexes: Structural, electrochemical and computational studies

• Main Authors: Phimphaka Harding, David J. Harding, Rattawat Daengngern, Theeraphol Thurakitsaree, Brian M. Schutte, Michael J. Shaw, Yuthana Tantirungrotechai
• Format: Journal
• Published: 2018
• Subjects: Chemistry; Materials Science
• Online Access: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84863775610&origin=inward; http://cmuir.cmu.ac.th/jspui/handle/6653943832/51481
• Institution: Chiang Mai University

Structural, electrochemical, spectroelectrochemical, magnetic and spectroscopic studies are reported for the octahedral cobalt β-diketonate complexes, [Co(β-diketonate)2(N-N)] {β-diketonate = 2,2,6,6-tetramethylheptane-3,5-dionate (tmhd); N-N = 1,10-phenanthroline (phen) 1, 2,2′-bipyridine (2,2′-bpy...