Synthesis and characterization of redox-active tris(pyrazolyl)borate cobalt complexes
The reaction of CoX2(X = Cl, Br, NO3) with KTpPh2in tetrahydrofuran (THF) yields the half-sandwich compounds [TpPh2CoX] (X = Cl 1, Br 2, NO33). The reaction of [TpPh2CoBr] with NaX (X = N3, NO2) or potassium thiocyanate (KNCS) permits isolation of [TpPh2CoX] (X = N34, NCS 5, NO26). In contrast, the...
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| Main Authors: | , , , , |
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| Format: | Journal |
| Published: |
2018
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| Subjects: | |
| Online Access: | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85034350197&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/59481 |
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| Institution: | Chiang Mai University |