Synthesis and characterization of redox-active tris(pyrazolyl)borate cobalt complexes
The reaction of CoX2 (X = Cl, Br, NO3) with KTp Ph2 in tetrahydrofuran (THF) yields the half-sandwich compounds [TpPh2CoX] (X = Cl 1, Br 2, NO33). The reaction of [TpPh2CoBr] with NaX (X = N3, NO2) or potassium thiocyanate (KNCS) permits isolation of [TpPh2CoX] (X = N 34, NCS 5, NO26). In contrast,...
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Main Authors: | , , , , |
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Format: | Article |
Language: | English |
Published: |
2014
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Online Access: | http://www.scopus.com/inward/record.url?eid=2-s2.0-59949083037&partnerID=40&md5=8cfcfd055569ab220ed02c3dbff99330 http://cmuir.cmu.ac.th/handle/6653943832/5933 |
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Institution: | Chiang Mai University |
Language: | English |