Synthesis and characterization of redox-active tris(pyrazolyl)borate cobalt complexes

The reaction of CoX2 (X = Cl, Br, NO3) with KTp Ph2 in tetrahydrofuran (THF) yields the half-sandwich compounds [TpPh2CoX] (X = Cl 1, Br 2, NO33). The reaction of [TpPh2CoBr] with NaX (X = N3, NO2) or potassium thiocyanate (KNCS) permits isolation of [TpPh2CoX] (X = N 34, NCS 5, NO26). In contrast,...

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Bibliographic Details
Main Authors: Harding D.J., Harding P., Daengngern R., Yimklan S., Adams H.
Format: Article
Language:English
Published: 2014
Online Access:http://www.scopus.com/inward/record.url?eid=2-s2.0-59949083037&partnerID=40&md5=8cfcfd055569ab220ed02c3dbff99330
http://cmuir.cmu.ac.th/handle/6653943832/5933
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Institution: Chiang Mai University
Language: English

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