Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation

© 2014 Elsevier Ltd. All rights reserved. A rapid and efficient method for preparation of C2-symmetrical 1,3,5-triazine polycarboxylate ligands was developed. The reactions included either selective mono- or di-substitution of 2,4,6-trichloro-1,3,5-triazine with various nucleophiles containing carbo...

Full description

Saved in:
Bibliographic Details
Main Authors: Watcharee Funfuenha, Wong Phakhodee, Mookda Pattarawarapan
Format: Journal
Published: 2018
Subjects:
Online Access:https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84949124339&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/53182
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Chiang Mai University
Description
Summary:© 2014 Elsevier Ltd. All rights reserved. A rapid and efficient method for preparation of C2-symmetrical 1,3,5-triazine polycarboxylate ligands was developed. The reactions included either selective mono- or di-substitution of 2,4,6-trichloro-1,3,5-triazine with various nucleophiles containing carboxyl group(s), followed by nucleophilic displacement of the remained chloride(s) in aqueous media under microwave irradiation. Novel C2-symmetrical tripodal ligands were afforded in good yields and purities under short reaction time with simple work-up, which are potentially useful as structural directing units in metal-organic frameworks.