Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
© 2014 Elsevier Ltd. All rights reserved. A rapid and efficient method for preparation of C2-symmetrical 1,3,5-triazine polycarboxylate ligands was developed. The reactions included either selective mono- or di-substitution of 2,4,6-trichloro-1,3,5-triazine with various nucleophiles containing carbo...
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th-cmuir.6653943832-531822018-09-04T10:00:17Z Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation Watcharee Funfuenha Wong Phakhodee Mookda Pattarawarapan Biochemistry, Genetics and Molecular Biology Chemistry Pharmacology, Toxicology and Pharmaceutics © 2014 Elsevier Ltd. All rights reserved. A rapid and efficient method for preparation of C2-symmetrical 1,3,5-triazine polycarboxylate ligands was developed. The reactions included either selective mono- or di-substitution of 2,4,6-trichloro-1,3,5-triazine with various nucleophiles containing carboxyl group(s), followed by nucleophilic displacement of the remained chloride(s) in aqueous media under microwave irradiation. Novel C2-symmetrical tripodal ligands were afforded in good yields and purities under short reaction time with simple work-up, which are potentially useful as structural directing units in metal-organic frameworks. 2018-09-04T09:44:48Z 2018-09-04T09:44:48Z 2014-09-02 Journal 14645416 00404020 2-s2.0-84949124339 10.1016/j.tet.2014.06.127 https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84949124339&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/53182 |
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Biochemistry, Genetics and Molecular Biology Chemistry Pharmacology, Toxicology and Pharmaceutics Watcharee Funfuenha Wong Phakhodee Mookda Pattarawarapan Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation |
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© 2014 Elsevier Ltd. All rights reserved. A rapid and efficient method for preparation of C2-symmetrical 1,3,5-triazine polycarboxylate ligands was developed. The reactions included either selective mono- or di-substitution of 2,4,6-trichloro-1,3,5-triazine with various nucleophiles containing carboxyl group(s), followed by nucleophilic displacement of the remained chloride(s) in aqueous media under microwave irradiation. Novel C2-symmetrical tripodal ligands were afforded in good yields and purities under short reaction time with simple work-up, which are potentially useful as structural directing units in metal-organic frameworks. |
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Journal |
author |
Watcharee Funfuenha Wong Phakhodee Mookda Pattarawarapan |
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Watcharee Funfuenha Wong Phakhodee Mookda Pattarawarapan |
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Watcharee Funfuenha |
title |
Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation |
title_short |
Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation |
title_full |
Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation |
title_fullStr |
Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation |
title_full_unstemmed |
Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation |
title_sort |
facile and efficient synthesis of c<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation |
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2018 |
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https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84949124339&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/53182 |
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