Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation

© 2014 Elsevier Ltd. All rights reserved. A rapid and efficient method for preparation of C2-symmetrical 1,3,5-triazine polycarboxylate ligands was developed. The reactions included either selective mono- or di-substitution of 2,4,6-trichloro-1,3,5-triazine with various nucleophiles containing carbo...

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Main Authors: Watcharee Funfuenha, Wong Phakhodee, Mookda Pattarawarapan
Format: Journal
Published: 2018
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http://cmuir.cmu.ac.th/jspui/handle/6653943832/53182
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Institution: Chiang Mai University
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spelling th-cmuir.6653943832-531822018-09-04T10:00:17Z Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation Watcharee Funfuenha Wong Phakhodee Mookda Pattarawarapan Biochemistry, Genetics and Molecular Biology Chemistry Pharmacology, Toxicology and Pharmaceutics © 2014 Elsevier Ltd. All rights reserved. A rapid and efficient method for preparation of C2-symmetrical 1,3,5-triazine polycarboxylate ligands was developed. The reactions included either selective mono- or di-substitution of 2,4,6-trichloro-1,3,5-triazine with various nucleophiles containing carboxyl group(s), followed by nucleophilic displacement of the remained chloride(s) in aqueous media under microwave irradiation. Novel C2-symmetrical tripodal ligands were afforded in good yields and purities under short reaction time with simple work-up, which are potentially useful as structural directing units in metal-organic frameworks. 2018-09-04T09:44:48Z 2018-09-04T09:44:48Z 2014-09-02 Journal 14645416 00404020 2-s2.0-84949124339 10.1016/j.tet.2014.06.127 https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84949124339&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/53182
institution Chiang Mai University
building Chiang Mai University Library
country Thailand
collection CMU Intellectual Repository
topic Biochemistry, Genetics and Molecular Biology
Chemistry
Pharmacology, Toxicology and Pharmaceutics
spellingShingle Biochemistry, Genetics and Molecular Biology
Chemistry
Pharmacology, Toxicology and Pharmaceutics
Watcharee Funfuenha
Wong Phakhodee
Mookda Pattarawarapan
Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
description © 2014 Elsevier Ltd. All rights reserved. A rapid and efficient method for preparation of C2-symmetrical 1,3,5-triazine polycarboxylate ligands was developed. The reactions included either selective mono- or di-substitution of 2,4,6-trichloro-1,3,5-triazine with various nucleophiles containing carboxyl group(s), followed by nucleophilic displacement of the remained chloride(s) in aqueous media under microwave irradiation. Novel C2-symmetrical tripodal ligands were afforded in good yields and purities under short reaction time with simple work-up, which are potentially useful as structural directing units in metal-organic frameworks.
format Journal
author Watcharee Funfuenha
Wong Phakhodee
Mookda Pattarawarapan
author_facet Watcharee Funfuenha
Wong Phakhodee
Mookda Pattarawarapan
author_sort Watcharee Funfuenha
title Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
title_short Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
title_full Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
title_fullStr Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
title_full_unstemmed Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
title_sort facile and efficient synthesis of c<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
publishDate 2018
url https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84949124339&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/53182
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