Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer

A pillared-layered coordination polymer of formula Co(H2NCH 2CH2NH2)SO4 (1) has been synthesized under solvothermal condition, and fully characterized. The three-dimensional structure of 1 is built up from cobalt sulfate sheets, each of which is composed of regularly alternating CoO4N2 octahedra and...

وصف كامل

محفوظ في:
التفاصيل البيبلوغرافية
المؤلفون الرئيسيون: Lauchan S., Prior T.J., Meansiri S., Rujiwatra A.
التنسيق: مقال
اللغة:English
منشور في: 2014
الوصول للمادة أونلاين:http://www.scopus.com/inward/record.url?eid=2-s2.0-46649113934&partnerID=40&md5=adb811fe3ce0c2db9a90274dffe17364
http://cmuir.cmu.ac.th/handle/6653943832/5495
الوسوم: إضافة وسم
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المؤسسة: Chiang Mai University
اللغة: English
الوصف
الملخص:A pillared-layered coordination polymer of formula Co(H2NCH 2CH2NH2)SO4 (1) has been synthesized under solvothermal condition, and fully characterized. The three-dimensional structure of 1 is built up from cobalt sulfate sheets, each of which is composed of regularly alternating CoO4N2 octahedra and SO 4 tetrahedra, with ethylenediamine pillars connecting the adjacent sheets. The coordinate covalent and hydrogen bonds have been revealed to exhibit an important role in the organization of the structure. The compound is found to be thermally stable up to, and above, 573 K and exhibits paramagnetic behavior at room temperature. © 2008 Springer Science+Business Media, LLC.