Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer

Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer

A pillared-layered coordination polymer of formula Co(H2NCH 2CH2NH2)SO4 (1) has been synthesized under solvothermal condition, and fully characterized. The three-dimensional structure of 1 is built up from cobalt sulfate sheets, each of which is composed of regularly alternating CoO4N2 octahedra and...

Full description

Saved in:
Bibliographic Details
Main Authors: Lauchan S., Prior T.J., Meansiri S., Rujiwatra A.
Format: Article
Language:English
Published: 2014
Online Access:http://www.scopus.com/inward/record.url?eid=2-s2.0-46649113934&partnerID=40&md5=adb811fe3ce0c2db9a90274dffe17364
http://cmuir.cmu.ac.th/handle/6653943832/5495
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Chiang Mai University
Language: English
id th-cmuir.6653943832-5495
record_format dspace
spelling th-cmuir.6653943832-54952014-08-30T02:56:35Z Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer Lauchan S. Prior T.J. Meansiri S. Rujiwatra A. A pillared-layered coordination polymer of formula Co(H2NCH 2CH2NH2)SO4 (1) has been synthesized under solvothermal condition, and fully characterized. The three-dimensional structure of 1 is built up from cobalt sulfate sheets, each of which is composed of regularly alternating CoO4N2 octahedra and SO 4 tetrahedra, with ethylenediamine pillars connecting the adjacent sheets. The coordinate covalent and hydrogen bonds have been revealed to exhibit an important role in the organization of the structure. The compound is found to be thermally stable up to, and above, 573 K and exhibits paramagnetic behavior at room temperature. © 2008 Springer Science+Business Media, LLC. 2014-08-30T02:56:35Z 2014-08-30T02:56:35Z 2008 Article 15741443 10.1007/s10904-008-9208-x http://www.scopus.com/inward/record.url?eid=2-s2.0-46649113934&partnerID=40&md5=adb811fe3ce0c2db9a90274dffe17364 http://cmuir.cmu.ac.th/handle/6653943832/5495 English
institution Chiang Mai University
building Chiang Mai University Library
country Thailand
collection CMU Intellectual Repository
language English
description A pillared-layered coordination polymer of formula Co(H2NCH 2CH2NH2)SO4 (1) has been synthesized under solvothermal condition, and fully characterized. The three-dimensional structure of 1 is built up from cobalt sulfate sheets, each of which is composed of regularly alternating CoO4N2 octahedra and SO 4 tetrahedra, with ethylenediamine pillars connecting the adjacent sheets. The coordinate covalent and hydrogen bonds have been revealed to exhibit an important role in the organization of the structure. The compound is found to be thermally stable up to, and above, 573 K and exhibits paramagnetic behavior at room temperature. © 2008 Springer Science+Business Media, LLC.
format Article
author Lauchan S.
Prior T.J.
Meansiri S.
Rujiwatra A.
spellingShingle Lauchan S.
Prior T.J.
Meansiri S.
Rujiwatra A.
Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer
author_facet Lauchan S.
Prior T.J.
Meansiri S.
Rujiwatra A.
author_sort Lauchan S.
title Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer
title_short Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer
title_full Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer
title_fullStr Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer
title_full_unstemmed Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer
title_sort cobalt(ethylenediamine)sulfate: a pillared layered coordination polymer
publishDate 2014
url http://www.scopus.com/inward/record.url?eid=2-s2.0-46649113934&partnerID=40&md5=adb811fe3ce0c2db9a90274dffe17364
http://cmuir.cmu.ac.th/handle/6653943832/5495
_version_ 1681420436504576000

Similar Items