(1-Butyl-1,4-diaza-bicyclo-[2.2.2]octon-1-ium-N 4) trichloridocobalt(II)
The title compound, [Co(C10H21N2)Cl3], was obtained as the by-product of the attempted synthesis of a cobalt sulfate framework using 1,4-diaza-bicyclo-[2.2.2]octane as an organic template. The asymmetric unit comprises two distinct mol-ecules, and in each, the cobalt(II) ions are tetra-hedrally coor...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
2014
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| Online Access: | http://www.scopus.com/inward/record.url?eid=2-s2.0-62149115690&partnerID=40&md5=bf6a2abc4fef2b40b40e978b23d72b08 http://cmuir.cmu.ac.th/handle/6653943832/5922 |
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| Institution: | Chiang Mai University |
| Language: | English |
| Summary: | The title compound, [Co(C10H21N2)Cl3], was obtained as the by-product of the attempted synthesis of a cobalt sulfate framework using 1,4-diaza-bicyclo-[2.2.2]octane as an organic template. The asymmetric unit comprises two distinct mol-ecules, and in each, the cobalt(II) ions are tetra-hedrally coordinated by three chloride anions and one 1-butyl-diaza-bicyclo-[2.2.2]octan-1-ium cation. The organic ligands are generated in situ, and exhibit two forms differentiated by the eclipsed and staggered conformations of the butyl groups. These mol-ecules inter-act by way of C - H⋯Cl hydrogen bonds, forming a three-dimensional hydrogen-bonding array. |
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