(1-Butyl-1,4-diaza-bicyclo-[2.2.2]octon-1-ium-N 4) trichloridocobalt(II)
The title compound, [Co(C10H21N2)Cl3], was obtained as the by-product of the attempted synthesis of a cobalt sulfate framework using 1,4-diaza-bicyclo-[2.2.2]octane as an organic template. The asymmetric unit comprises two distinct mol-ecules, and in each, the cobalt(II) ions are tetra-hedrally coor...
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2014
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th-cmuir.6653943832-59222014-08-30T03:23:37Z (1-Butyl-1,4-diaza-bicyclo-[2.2.2]octon-1-ium-N 4) trichloridocobalt(II) Luachan S. Yotnoi B. Prior T.J. Rujiwatra A. The title compound, [Co(C10H21N2)Cl3], was obtained as the by-product of the attempted synthesis of a cobalt sulfate framework using 1,4-diaza-bicyclo-[2.2.2]octane as an organic template. The asymmetric unit comprises two distinct mol-ecules, and in each, the cobalt(II) ions are tetra-hedrally coordinated by three chloride anions and one 1-butyl-diaza-bicyclo-[2.2.2]octan-1-ium cation. The organic ligands are generated in situ, and exhibit two forms differentiated by the eclipsed and staggered conformations of the butyl groups. These mol-ecules inter-act by way of C - H⋯Cl hydrogen bonds, forming a three-dimensional hydrogen-bonding array. 2014-08-30T03:23:37Z 2014-08-30T03:23:37Z 2009 Article 16005368 10.1107/S1600536809005893 http://www.scopus.com/inward/record.url?eid=2-s2.0-62149115690&partnerID=40&md5=bf6a2abc4fef2b40b40e978b23d72b08 http://cmuir.cmu.ac.th/handle/6653943832/5922 English |
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Thailand |
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English |
| description |
The title compound, [Co(C10H21N2)Cl3], was obtained as the by-product of the attempted synthesis of a cobalt sulfate framework using 1,4-diaza-bicyclo-[2.2.2]octane as an organic template. The asymmetric unit comprises two distinct mol-ecules, and in each, the cobalt(II) ions are tetra-hedrally coordinated by three chloride anions and one 1-butyl-diaza-bicyclo-[2.2.2]octan-1-ium cation. The organic ligands are generated in situ, and exhibit two forms differentiated by the eclipsed and staggered conformations of the butyl groups. These mol-ecules inter-act by way of C - H⋯Cl hydrogen bonds, forming a three-dimensional hydrogen-bonding array. |
| format |
Article |
| author |
Luachan S. Yotnoi B. Prior T.J. Rujiwatra A. |
| spellingShingle |
Luachan S. Yotnoi B. Prior T.J. Rujiwatra A. (1-Butyl-1,4-diaza-bicyclo-[2.2.2]octon-1-ium-N 4) trichloridocobalt(II) |
| author_facet |
Luachan S. Yotnoi B. Prior T.J. Rujiwatra A. |
| author_sort |
Luachan S. |
| title |
(1-Butyl-1,4-diaza-bicyclo-[2.2.2]octon-1-ium-N 4) trichloridocobalt(II) |
| title_short |
(1-Butyl-1,4-diaza-bicyclo-[2.2.2]octon-1-ium-N 4) trichloridocobalt(II) |
| title_full |
(1-Butyl-1,4-diaza-bicyclo-[2.2.2]octon-1-ium-N 4) trichloridocobalt(II) |
| title_fullStr |
(1-Butyl-1,4-diaza-bicyclo-[2.2.2]octon-1-ium-N 4) trichloridocobalt(II) |
| title_full_unstemmed |
(1-Butyl-1,4-diaza-bicyclo-[2.2.2]octon-1-ium-N 4) trichloridocobalt(II) |
| title_sort |
(1-butyl-1,4-diaza-bicyclo-[2.2.2]octon-1-ium-n 4) trichloridocobalt(ii) |
| publishDate |
2014 |
| url |
http://www.scopus.com/inward/record.url?eid=2-s2.0-62149115690&partnerID=40&md5=bf6a2abc4fef2b40b40e978b23d72b08 http://cmuir.cmu.ac.th/handle/6653943832/5922 |
| _version_ |
1681420516877926400 |