Synthesis of castanospermine

The diastereoselective synthesis of castanospermine is described in 11 synthetic steps from l-xylose. The borono-Mannich reaction between l-xylose, allylamine, and (E)-styrene boronic acid gives a tetrahydroxy amine with the desired configurations for C-6, C-7, C-8, and C-8a in the target molecule....

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Bibliographic Details
Main Authors: Theeraphan Machan, Andrew S. Davis, Boonsom Liawruangrath, Stephen G. Pyne
Format: Journal
Published: 2018
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Online Access:https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=39149142197&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/60178
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Institution: Chiang Mai University