Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]

The reaction of bis-(1,3-diphenylpropane-1,3-dionato)cobalt(II), [Co(dbm)2], with bis-(diphenyl-phosphino)ethane (dppe) affords the coordination polymer catena-poly[[bis-(1,3-diphenyl-propane-1,3-dionato-2 O,O′)cobalt(II)] - ethyl-enebis(diphenyl-phosphine oxide)-2 O:O′], trans-[Co(C15H11O2)2(C26H24...

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Main Authors:	David J. Harding, Phimphaka Harding, Theerapol Thurakitseree, Harry Adams
Format:	Journal
Published:	2018
Subjects:	Biochemistry, Genetics and Molecular Biology Physics and Astronomy
Online Access:	https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=34147098501&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/60911
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Institution:	Chiang Mai University

id	th-cmuir.6653943832-60911
record_format	dspace
spelling	th-cmuir.6653943832-609112018-09-10T04:10:48Z Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2] David J. Harding Phimphaka Harding Theerapol Thurakitseree Harry Adams Biochemistry, Genetics and Molecular Biology Physics and Astronomy The reaction of bis-(1,3-diphenylpropane-1,3-dionato)cobalt(II), [Co(dbm)2], with bis-(diphenyl-phosphino)ethane (dppe) affords the coordination polymer catena-poly[[bis-(1,3-diphenyl-propane-1,3-dionato-2 O,O′)cobalt(II)] - ethyl-enebis(diphenyl-phosphine oxide)-2 O:O′], trans-[Co(C15H11O2)2(C26H24O2P2)] n, as a result of oxidation of the diphos-phine. The Co atom is octa-hedral, with a CoO6 coordination sphere, and the chelating dbm ligands adopt a trans configuration. The Co atom also lies on a centre of inversion, with a further symmetry centre bis-ecting the bridging ethyl-enebis(diphenyl-phosphine oxide) ligand. © International Union of Crystallography 2007. 2018-09-10T04:01:11Z 2018-09-10T04:01:11Z 2007-03-10 Journal 01082701 01082701 2-s2.0-34147098501 10.1107/S010827010700933X https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=34147098501&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/60911
institution	Chiang Mai University
building	Chiang Mai University Library
country	Thailand
collection	CMU Intellectual Repository
topic	Biochemistry, Genetics and Molecular Biology Physics and Astronomy
spellingShingle	Biochemistry, Genetics and Molecular Biology Physics and Astronomy David J. Harding Phimphaka Harding Theerapol Thurakitseree Harry Adams Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]
description	The reaction of bis-(1,3-diphenylpropane-1,3-dionato)cobalt(II), [Co(dbm)2], with bis-(diphenyl-phosphino)ethane (dppe) affords the coordination polymer catena-poly[[bis-(1,3-diphenyl-propane-1,3-dionato-2 O,O′)cobalt(II)] - ethyl-enebis(diphenyl-phosphine oxide)-2 O:O′], trans-[Co(C15H11O2)2(C26H24O2P2)] n, as a result of oxidation of the diphos-phine. The Co atom is octa-hedral, with a CoO6 coordination sphere, and the chelating dbm ligands adopt a trans configuration. The Co atom also lies on a centre of inversion, with a further symmetry centre bis-ecting the bridging ethyl-enebis(diphenyl-phosphine oxide) ligand. © International Union of Crystallography 2007.
format	Journal
author	David J. Harding Phimphaka Harding Theerapol Thurakitseree Harry Adams
author_facet	David J. Harding Phimphaka Harding Theerapol Thurakitseree Harry Adams
author_sort	David J. Harding
title	Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]
title_short	Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]
title_full	Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]
title_fullStr	Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]
title_full_unstemmed	Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]
title_sort	unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(ii), [co(dbm)2]
publishDate	2018
url	https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=34147098501&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/60911
_version_	1681425523314524160

Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]

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