Unexpected oxidation of a diphos-phine by bis-(1,3-diphenylpropane-1,3- dionato)-cobalt(II), [Co(dbm)2]

• Main Authors: David J. Harding, Phimphaka Harding, Theerapol Thurakitseree, Harry Adams
• Format: Journal
• Published: 2018
• Subjects: Biochemistry, Genetics and Molecular Biology; Physics and Astronomy
• Online Access: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=34147098501&origin=inward; http://cmuir.cmu.ac.th/jspui/handle/6653943832/60911
• Institution: Chiang Mai University

The reaction of bis-(1,3-diphenylpropane-1,3-dionato)cobalt(II), [Co(dbm)2], with bis-(diphenyl-phosphino)ethane (dppe) affords the coordination polymer catena-poly[[bis-(1,3-diphenyl-propane-1,3-dionato-2 O,O′)cobalt(II)] - ethyl-enebis(diphenyl-phosphine oxide)-2 O:O′], trans-[Co(C15H11O2)2(C26H24...