Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate

Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate

The reaction of 1,4-dibenzyl-1,4-diabicyclo [2.2.2] octane dichloroiodate (DBDDCI) with alkenes in the presence of oxygenated nucleophilic solvents (alcohols or H2O/CH3CN (1:1)) in mild and under catalyst free condition at room temperature led to the corresponding β-iodoethers and iodohydrines in g...

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Main Authors: Mohammad Alikarami, Somaye Mohammadnezhad, Zahra Abbasi
Language:English
Published: Science Faculty of Chiang Mai University 2019
Subjects:
1,4-dibenzyl-1
4-diazabicyclo[2.2.2]octane dichloroiodate
co-iodination
iodohydrines
β-iodoether
catalyst free
Online Access:http://it.science.cmu.ac.th/ejournal/dl.php?journal_id=6250
http://cmuir.cmu.ac.th/jspui/handle/6653943832/66167
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Language: English
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spelling th-cmuir.6653943832-661672019-08-21T09:18:23Z Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate Mohammad Alikarami Somaye Mohammadnezhad Zahra Abbasi 1,4-dibenzyl-1 4-diazabicyclo[2.2.2]octane dichloroiodate co-iodination iodohydrines β-iodoether catalyst free The reaction of 1,4-dibenzyl-1,4-diabicyclo [2.2.2] octane dichloroiodate (DBDDCI) with alkenes in the presence of oxygenated nucleophilic solvents (alcohols or H2O/CH3CN (1:1)) in mild and under catalyst free condition at room temperature led to the corresponding β-iodoethers and iodohydrines in good to excellent yield. 2019-08-21T09:18:23Z 2019-08-21T09:18:23Z 2015 Chiang Mai Journal of Science 42, 4 (Oct 2015), 957 - 962 0125-2526 http://it.science.cmu.ac.th/ejournal/dl.php?journal_id=6250 http://cmuir.cmu.ac.th/jspui/handle/6653943832/66167 Eng Science Faculty of Chiang Mai University
institution Chiang Mai University
building Chiang Mai University Library
country Thailand
collection CMU Intellectual Repository
language English
topic 1,4-dibenzyl-1
4-diazabicyclo[2.2.2]octane dichloroiodate
co-iodination
iodohydrines
β-iodoether
catalyst free
spellingShingle 1,4-dibenzyl-1
4-diazabicyclo[2.2.2]octane dichloroiodate
co-iodination
iodohydrines
β-iodoether
catalyst free
Mohammad Alikarami
Somaye Mohammadnezhad
Zahra Abbasi
Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate
description The reaction of 1,4-dibenzyl-1,4-diabicyclo [2.2.2] octane dichloroiodate (DBDDCI) with alkenes in the presence of oxygenated nucleophilic solvents (alcohols or H2O/CH3CN (1:1)) in mild and under catalyst free condition at room temperature led to the corresponding β-iodoethers and iodohydrines in good to excellent yield.
author Mohammad Alikarami
Somaye Mohammadnezhad
Zahra Abbasi
author_facet Mohammad Alikarami
Somaye Mohammadnezhad
Zahra Abbasi
author_sort Mohammad Alikarami
title Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate
title_short Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate
title_full Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate
title_fullStr Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate
title_full_unstemmed Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate
title_sort regioselective 1,2-alkoxy and hydroxy iodination of alkenes by 1,4-dibenzyl-1,4-diazabicyclo[2.2.2]octane dichloroiodate
publisher Science Faculty of Chiang Mai University
publishDate 2019
url http://it.science.cmu.ac.th/ejournal/dl.php?journal_id=6250
http://cmuir.cmu.ac.th/jspui/handle/6653943832/66167
_version_ 1681426404486414336

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