Regioselective 1,2-Alkoxy and Hydroxy Iodination of Alkenes by 1,4-Dibenzyl-1,4-Diazabicyclo[2.2.2]Octane Dichloroiodate

• Main Authors: Mohammad Alikarami, Somaye Mohammadnezhad, Zahra Abbasi
• Language: English
• Published: Science Faculty of Chiang Mai University 2019
• Subjects: 1,4-dibenzyl-1; 4-diazabicyclo[2.2.2]octane dichloroiodate; co-iodination; iodohydrines; β-iodoether; catalyst free
• Online Access: http://it.science.cmu.ac.th/ejournal/dl.php?journal_id=6250; http://cmuir.cmu.ac.th/jspui/handle/6653943832/66167
• Institution: Chiang Mai University

The reaction of 1,4-dibenzyl-1,4-diabicyclo [2.2.2] octane dichloroiodate (DBDDCI) with alkenes in the presence of oxygenated nucleophilic solvents (alcohols or H2O/CH3CN (1:1)) in mild and under catalyst free condition at room temperature led to the corresponding β-iodoethers and iodohydrines in g...