Synthesis of deepoxy-4,5-didehydromethylenomycin a and methylenomycin a methyl esters

[±]-Deepoxy-4,5-didehydromethylenomycin A methyl ester 8 and [±] -methylenomycin A methyl ester 9 are synthesized from anthracene adduct 2 via a common intermediate 13. Flash vacuum pyrolysis of adduct 13 gives 8, while stereospecific epoxidation of 13 followed by pyrolysis yields 9. © 1989.

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Main Authors:	C. Mahidol, C. Thebtaranonth, Y. Thebtaranonth, C. Yenjai
Other Authors:	Mahidol University
Format:	Article
Published:	2018
Subjects:	Biochemistry, Genetics and Molecular Biology Chemistry Pharmacology, Toxicology and Pharmaceutics
Online Access:	https://repository.li.mahidol.ac.th/handle/123456789/15719
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Institution:	Mahidol University

id	th-mahidol.15719
record_format	dspace
spelling	th-mahidol.157192018-06-14T16:17:30Z Synthesis of deepoxy-4,5-didehydromethylenomycin a and methylenomycin a methyl esters C. Mahidol C. Thebtaranonth Y. Thebtaranonth C. Yenjai Mahidol University Biochemistry, Genetics and Molecular Biology Chemistry Pharmacology, Toxicology and Pharmaceutics [±]-Deepoxy-4,5-didehydromethylenomycin A methyl ester 8 and [±] -methylenomycin A methyl ester 9 are synthesized from anthracene adduct 2 via a common intermediate 13. Flash vacuum pyrolysis of adduct 13 gives 8, while stereospecific epoxidation of 13 followed by pyrolysis yields 9. © 1989. 2018-06-14T09:12:53Z 2018-06-14T09:12:53Z 1989-01-01 Article Tetrahedron Letters. Vol.30, No.29 (1989), 3857-3860 10.1016/S0040-4039(01)80677-8 00404039 2-s2.0-0024359306 https://repository.li.mahidol.ac.th/handle/123456789/15719 Mahidol University SCOPUS https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0024359306&origin=inward
institution	Mahidol University
building	Mahidol University Library
continent	Asia
country	Thailand Thailand
content_provider	Mahidol University Library
collection	Mahidol University Institutional Repository
topic	Biochemistry, Genetics and Molecular Biology Chemistry Pharmacology, Toxicology and Pharmaceutics
spellingShingle	Biochemistry, Genetics and Molecular Biology Chemistry Pharmacology, Toxicology and Pharmaceutics C. Mahidol C. Thebtaranonth Y. Thebtaranonth C. Yenjai Synthesis of deepoxy-4,5-didehydromethylenomycin a and methylenomycin a methyl esters
description	[±]-Deepoxy-4,5-didehydromethylenomycin A methyl ester 8 and [±] -methylenomycin A methyl ester 9 are synthesized from anthracene adduct 2 via a common intermediate 13. Flash vacuum pyrolysis of adduct 13 gives 8, while stereospecific epoxidation of 13 followed by pyrolysis yields 9. © 1989.
author2	Mahidol University
author_facet	Mahidol University C. Mahidol C. Thebtaranonth Y. Thebtaranonth C. Yenjai
format	Article
author	C. Mahidol C. Thebtaranonth Y. Thebtaranonth C. Yenjai
author_sort	C. Mahidol
title	Synthesis of deepoxy-4,5-didehydromethylenomycin a and methylenomycin a methyl esters
title_short	Synthesis of deepoxy-4,5-didehydromethylenomycin a and methylenomycin a methyl esters
title_full	Synthesis of deepoxy-4,5-didehydromethylenomycin a and methylenomycin a methyl esters
title_fullStr	Synthesis of deepoxy-4,5-didehydromethylenomycin a and methylenomycin a methyl esters
title_full_unstemmed	Synthesis of deepoxy-4,5-didehydromethylenomycin a and methylenomycin a methyl esters
title_sort	synthesis of deepoxy-4,5-didehydromethylenomycin a and methylenomycin a methyl esters
publishDate	2018
url	https://repository.li.mahidol.ac.th/handle/123456789/15719
_version_	1763489560894898176

Synthesis of deepoxy-4,5-didehydromethylenomycin a and methylenomycin a methyl esters

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