Synthesis of deepoxy-4,5-didehydromethylenomycin a and methylenomycin a methyl esters
[±]-Deepoxy-4,5-didehydromethylenomycin A methyl ester 8 and [±] -methylenomycin A methyl ester 9 are synthesized from anthracene adduct 2 via a common intermediate 13. Flash vacuum pyrolysis of adduct 13 gives 8, while stereospecific epoxidation of 13 followed by pyrolysis yields 9. © 1989.
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| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Article |
| Published: |
2018
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| Subjects: | |
| Online Access: | https://repository.li.mahidol.ac.th/handle/123456789/15719 |
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| Institution: | Mahidol University |