Reactivity of chlorinating agents/PPh<inf>3</inf>for the chlorination of alcohols and carboxylic acids: a comparative study

The reactivity of chlorinating agents was examined with the aid of1H NMR using competitive reactions between selected chlorinating agents and CBr4towards alcohols and carboxylic acids. The reactivity was greatly dependent on the type of substituent on the chlorinating agents. COCCl3and CN substitute...

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Main Authors: Wanchai Pluempanupat, Oraphin Chantarasriwong, Piyada Taboonpong, Doo Ok Jang, Warinthorn Chavasiri
Other Authors: Mahidol University
Format: Article
Published: 2018
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Online Access:https://repository.li.mahidol.ac.th/handle/123456789/24267
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spelling th-mahidol.242672018-08-24T09:16:05Z Reactivity of chlorinating agents/PPh<inf>3</inf>for the chlorination of alcohols and carboxylic acids: a comparative study Wanchai Pluempanupat Oraphin Chantarasriwong Piyada Taboonpong Doo Ok Jang Warinthorn Chavasiri Mahidol University Yonsei University Wonju Campus Biochemistry, Genetics and Molecular Biology Chemistry Pharmacology, Toxicology and Pharmaceutics The reactivity of chlorinating agents was examined with the aid of1H NMR using competitive reactions between selected chlorinating agents and CBr4towards alcohols and carboxylic acids. The reactivity was greatly dependent on the type of substituent on the chlorinating agents. COCCl3and CN substituted trichloromethyl groups enhanced the reactivity of the chlorinating agent with PPh3for the chlorination of alcohols and carboxylic acids. © 2006 Elsevier Ltd. All rights reserved. 2018-08-24T01:43:50Z 2018-08-24T01:43:50Z 2007-01-08 Article Tetrahedron Letters. Vol.48, No.2 (2007), 223-226 10.1016/j.tetlet.2006.11.060 00404039 2-s2.0-33845221264 https://repository.li.mahidol.ac.th/handle/123456789/24267 Mahidol University SCOPUS https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=33845221264&origin=inward
institution Mahidol University
building Mahidol University Library
continent Asia
country Thailand
Thailand
content_provider Mahidol University Library
collection Mahidol University Institutional Repository
topic Biochemistry, Genetics and Molecular Biology
Chemistry
Pharmacology, Toxicology and Pharmaceutics
spellingShingle Biochemistry, Genetics and Molecular Biology
Chemistry
Pharmacology, Toxicology and Pharmaceutics
Wanchai Pluempanupat
Oraphin Chantarasriwong
Piyada Taboonpong
Doo Ok Jang
Warinthorn Chavasiri
Reactivity of chlorinating agents/PPh<inf>3</inf>for the chlorination of alcohols and carboxylic acids: a comparative study
description The reactivity of chlorinating agents was examined with the aid of1H NMR using competitive reactions between selected chlorinating agents and CBr4towards alcohols and carboxylic acids. The reactivity was greatly dependent on the type of substituent on the chlorinating agents. COCCl3and CN substituted trichloromethyl groups enhanced the reactivity of the chlorinating agent with PPh3for the chlorination of alcohols and carboxylic acids. © 2006 Elsevier Ltd. All rights reserved.
author2 Mahidol University
author_facet Mahidol University
Wanchai Pluempanupat
Oraphin Chantarasriwong
Piyada Taboonpong
Doo Ok Jang
Warinthorn Chavasiri
format Article
author Wanchai Pluempanupat
Oraphin Chantarasriwong
Piyada Taboonpong
Doo Ok Jang
Warinthorn Chavasiri
author_sort Wanchai Pluempanupat
title Reactivity of chlorinating agents/PPh<inf>3</inf>for the chlorination of alcohols and carboxylic acids: a comparative study
title_short Reactivity of chlorinating agents/PPh<inf>3</inf>for the chlorination of alcohols and carboxylic acids: a comparative study
title_full Reactivity of chlorinating agents/PPh<inf>3</inf>for the chlorination of alcohols and carboxylic acids: a comparative study
title_fullStr Reactivity of chlorinating agents/PPh<inf>3</inf>for the chlorination of alcohols and carboxylic acids: a comparative study
title_full_unstemmed Reactivity of chlorinating agents/PPh<inf>3</inf>for the chlorination of alcohols and carboxylic acids: a comparative study
title_sort reactivity of chlorinating agents/pph<inf>3</inf>for the chlorination of alcohols and carboxylic acids: a comparative study
publishDate 2018
url https://repository.li.mahidol.ac.th/handle/123456789/24267
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