Application of the hypervalent iodine reagent to the synthesis of some pentasubstituted aporphine alkaloids

Application of the hypervalent iodine reagent to the synthesis of some pentasubstituted aporphine alkaloids

The oxidative biaryl coupling of various N-substituted 1- benzyltetrahydroisoquinolines to the corresponding aporphines by the hypervalent iodine reagent was studied. The study sheds light on the unifying mechanism of the reaction illustrating the requirement of the p-p coupling via the six-membered...

Full description

Saved in:
Bibliographic Details
Main Authors: Ratchanok Pingaew, Somsak Ruchirawat
Other Authors: Mahidol University
Format: Article
Published: 2018
Subjects:
Chemistry
Online Access:https://repository.li.mahidol.ac.th/handle/123456789/24337
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Mahidol University
id th-mahidol.24337
record_format dspace
spelling th-mahidol.243372018-08-24T08:45:55Z Application of the hypervalent iodine reagent to the synthesis of some pentasubstituted aporphine alkaloids Ratchanok Pingaew Somsak Ruchirawat Mahidol University Chulabhorn Research Institute The Institute of Science and Technology for Research and Development, Mahidol University Chemistry The oxidative biaryl coupling of various N-substituted 1- benzyltetrahydroisoquinolines to the corresponding aporphines by the hypervalent iodine reagent was studied. The study sheds light on the unifying mechanism of the reaction illustrating the requirement of the p-p coupling via the six-membered transition state as the initial step. The finding was applied to the synthesis of some pentasubstituted aporphine alkaloids. © Georg Thieme Verlag Stuttgart. 2018-08-24T01:45:55Z 2018-08-24T01:45:55Z 2007-09-17 Article Synlett. No.15 (2007), 2363-2366 10.1055/s-2007-985596 09365214 2-s2.0-34948839846 https://repository.li.mahidol.ac.th/handle/123456789/24337 Mahidol University SCOPUS https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=34948839846&origin=inward
institution Mahidol University
building Mahidol University Library
continent Asia
country Thailand
Thailand
content_provider Mahidol University Library
collection Mahidol University Institutional Repository
topic Chemistry
spellingShingle Chemistry
Ratchanok Pingaew
Somsak Ruchirawat
Application of the hypervalent iodine reagent to the synthesis of some pentasubstituted aporphine alkaloids
description The oxidative biaryl coupling of various N-substituted 1- benzyltetrahydroisoquinolines to the corresponding aporphines by the hypervalent iodine reagent was studied. The study sheds light on the unifying mechanism of the reaction illustrating the requirement of the p-p coupling via the six-membered transition state as the initial step. The finding was applied to the synthesis of some pentasubstituted aporphine alkaloids. © Georg Thieme Verlag Stuttgart.
author2 Mahidol University
author_facet Mahidol University
Ratchanok Pingaew
Somsak Ruchirawat
format Article
author Ratchanok Pingaew
Somsak Ruchirawat
author_sort Ratchanok Pingaew
title Application of the hypervalent iodine reagent to the synthesis of some pentasubstituted aporphine alkaloids
title_short Application of the hypervalent iodine reagent to the synthesis of some pentasubstituted aporphine alkaloids
title_full Application of the hypervalent iodine reagent to the synthesis of some pentasubstituted aporphine alkaloids
title_fullStr Application of the hypervalent iodine reagent to the synthesis of some pentasubstituted aporphine alkaloids
title_full_unstemmed Application of the hypervalent iodine reagent to the synthesis of some pentasubstituted aporphine alkaloids
title_sort application of the hypervalent iodine reagent to the synthesis of some pentasubstituted aporphine alkaloids
publishDate 2018
url https://repository.li.mahidol.ac.th/handle/123456789/24337
_version_ 1763496704240254976

Similar Items