Incorporation of dioxygen into the hydroxylated product during the C-C single bond cleavage of 1,2-bis(p-methoxyphenyl)propane-1,3-diol catalysed by hemin. A novel model system for the hemoprotein ligninase
Oxidation of the lignin model compound 1,2-bis(p-methoxyphenyl)propane-1,3- diol (1) catalysed by hemin in the presence of t-butyl hydroperoxide and18O2yielded p-methoxyphenylethane-1,2-diol (2) with 83%18O incorporation into the newly formed hydroxy group and p-anisaldehyde (3) as the initial Cα-Cβ...
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| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Article |
| Published: |
2018
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| Subjects: | |
| Online Access: | https://repository.li.mahidol.ac.th/handle/123456789/30756 |
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| Institution: | Mahidol University |