Incorporation of dioxygen into the hydroxylated product during the C-C single bond cleavage of 1,2-bis(p-methoxyphenyl)propane-1,3-diol catalysed by hemin. A novel model system for the hemoprotein ligninase

Oxidation of the lignin model compound 1,2-bis(p-methoxyphenyl)propane-1,3- diol (1) catalysed by hemin in the presence of t-butyl hydroperoxide and18O2yielded p-methoxyphenylethane-1,2-diol (2) with 83%18O incorporation into the newly formed hydroxy group and p-anisaldehyde (3) as the initial Cα-Cβ...

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Main Authors:	Tsuyoshi Habe, Mikio Shimada, Tadashi Okamoto, Bhinyo Panijpan, Takayoshi Higuchi
Other Authors:	Kyoto University
Format:	Article
Published:	2018
Subjects:	Biochemistry, Genetics and Molecular Biology
Online Access:	https://repository.li.mahidol.ac.th/handle/123456789/30756
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Institution:	Mahidol University

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spelling	th-mahidol.307562018-10-12T14:47:36Z Incorporation of dioxygen into the hydroxylated product during the C-C single bond cleavage of 1,2-bis(p-methoxyphenyl)propane-1,3-diol catalysed by hemin. A novel model system for the hemoprotein ligninase Tsuyoshi Habe Mikio Shimada Tadashi Okamoto Bhinyo Panijpan Takayoshi Higuchi Kyoto University Mahidol University Biochemistry, Genetics and Molecular Biology Oxidation of the lignin model compound 1,2-bis(p-methoxyphenyl)propane-1,3- diol (1) catalysed by hemin in the presence of t-butyl hydroperoxide and18O2yielded p-methoxyphenylethane-1,2-diol (2) with 83%18O incorporation into the newly formed hydroxy group and p-anisaldehyde (3) as the initial Cα-Cβbond cleavage products. 2018-10-12T07:47:36Z 2018-10-12T07:47:36Z 1985-01-01 Article Journal of the Chemical Society, Chemical Communications. No.19 (1985), 1323-1324 10.1039/C39850001323 00224936 2-s2.0-37049095685 https://repository.li.mahidol.ac.th/handle/123456789/30756 Mahidol University SCOPUS https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=37049095685&origin=inward
institution	Mahidol University
building	Mahidol University Library
continent	Asia
country	Thailand Thailand
content_provider	Mahidol University Library
collection	Mahidol University Institutional Repository
topic	Biochemistry, Genetics and Molecular Biology
spellingShingle	Biochemistry, Genetics and Molecular Biology Tsuyoshi Habe Mikio Shimada Tadashi Okamoto Bhinyo Panijpan Takayoshi Higuchi Incorporation of dioxygen into the hydroxylated product during the C-C single bond cleavage of 1,2-bis(p-methoxyphenyl)propane-1,3-diol catalysed by hemin. A novel model system for the hemoprotein ligninase
description	Oxidation of the lignin model compound 1,2-bis(p-methoxyphenyl)propane-1,3- diol (1) catalysed by hemin in the presence of t-butyl hydroperoxide and18O2yielded p-methoxyphenylethane-1,2-diol (2) with 83%18O incorporation into the newly formed hydroxy group and p-anisaldehyde (3) as the initial Cα-Cβbond cleavage products.
author2	Kyoto University
author_facet	Kyoto University Tsuyoshi Habe Mikio Shimada Tadashi Okamoto Bhinyo Panijpan Takayoshi Higuchi
format	Article
author	Tsuyoshi Habe Mikio Shimada Tadashi Okamoto Bhinyo Panijpan Takayoshi Higuchi
author_sort	Tsuyoshi Habe
title	Incorporation of dioxygen into the hydroxylated product during the C-C single bond cleavage of 1,2-bis(p-methoxyphenyl)propane-1,3-diol catalysed by hemin. A novel model system for the hemoprotein ligninase
title_short	Incorporation of dioxygen into the hydroxylated product during the C-C single bond cleavage of 1,2-bis(p-methoxyphenyl)propane-1,3-diol catalysed by hemin. A novel model system for the hemoprotein ligninase
title_full	Incorporation of dioxygen into the hydroxylated product during the C-C single bond cleavage of 1,2-bis(p-methoxyphenyl)propane-1,3-diol catalysed by hemin. A novel model system for the hemoprotein ligninase
title_fullStr	Incorporation of dioxygen into the hydroxylated product during the C-C single bond cleavage of 1,2-bis(p-methoxyphenyl)propane-1,3-diol catalysed by hemin. A novel model system for the hemoprotein ligninase
title_full_unstemmed	Incorporation of dioxygen into the hydroxylated product during the C-C single bond cleavage of 1,2-bis(p-methoxyphenyl)propane-1,3-diol catalysed by hemin. A novel model system for the hemoprotein ligninase
title_sort	incorporation of dioxygen into the hydroxylated product during the c-c single bond cleavage of 1,2-bis(p-methoxyphenyl)propane-1,3-diol catalysed by hemin. a novel model system for the hemoprotein ligninase
publishDate	2018
url	https://repository.li.mahidol.ac.th/handle/123456789/30756
_version_	1763491009986035712

Incorporation of dioxygen into the hydroxylated product during the C-C single bond cleavage of 1,2-bis(p-methoxyphenyl)propane-1,3-diol catalysed by hemin. A novel model system for the hemoprotein ligninase

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