Bi(OTf)<inf>3</inf> Enabled C-F Bond Cleavage in HFIP: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl)methane

Bi(OTf)<inf>3</inf> Enabled C-F Bond Cleavage in HFIP: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl)methane

© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Bismuth(III) trifluoromethanesulfonate [Bi(OTf)3] mediated mild electrophilic aromatic formylation utilizing difluoro(phenylsulfanyl)methane (PhSCF2H) as a formylating agent in hexafluoro-2-propanol (HFIP) as a recyclable ionizing solvent has b...

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Bibliographic Details
Main Authors: Nolan M. Betterley, Sutthichat Kerdphon, Suppisak Chaturonrutsamee, Sopanat Kongsriprapan, Panida Surawatanawong, Darunee Soorukram, Manat Pohmakotr, Pher G. Andersson, Vichai Reutrakul, Chutima Kuhakarn
Other Authors: Kasetsart University
Format: Article
Published: 2019
Subjects:
Chemistry
Online Access:https://repository.li.mahidol.ac.th/handle/123456789/45485
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Institution: Mahidol University
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Summary:© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Bismuth(III) trifluoromethanesulfonate [Bi(OTf)3] mediated mild electrophilic aromatic formylation utilizing difluoro(phenylsulfanyl)methane (PhSCF2H) as a formylating agent in hexafluoro-2-propanol (HFIP) as a recyclable ionizing solvent has been developed. The active formylating species was generated via C−F bond cleavage and was characterized to be a bis(phenylsulfanyl)methyl cation by experimental and computational 1H and 13C NMR.

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