Bi(OTf)<inf>3</inf> Enabled C-F Bond Cleavage in HFIP: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl)methane

Bi(OTf)<inf>3</inf> Enabled C-F Bond Cleavage in HFIP: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl)methane

© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Bismuth(III) trifluoromethanesulfonate [Bi(OTf)3] mediated mild electrophilic aromatic formylation utilizing difluoro(phenylsulfanyl)methane (PhSCF2H) as a formylating agent in hexafluoro-2-propanol (HFIP) as a recyclable ionizing solvent has b...

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Main Authors: Nolan M. Betterley, Sutthichat Kerdphon, Suppisak Chaturonrutsamee, Sopanat Kongsriprapan, Panida Surawatanawong, Darunee Soorukram, Manat Pohmakotr, Pher G. Andersson, Vichai Reutrakul, Chutima Kuhakarn
Other Authors: Kasetsart University
Format: Article
Published: 2019
Subjects:
Chemistry
Online Access:https://repository.li.mahidol.ac.th/handle/123456789/45485
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spelling th-mahidol.454852019-08-23T17:49:26Z Bi(OTf)<inf>3</inf> Enabled C-F Bond Cleavage in HFIP: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl)methane Nolan M. Betterley Sutthichat Kerdphon Suppisak Chaturonrutsamee Sopanat Kongsriprapan Panida Surawatanawong Darunee Soorukram Manat Pohmakotr Pher G. Andersson Vichai Reutrakul Chutima Kuhakarn Kasetsart University Mahidol University Arrhenius Laboratory International Laboratories Corp. Chemistry © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Bismuth(III) trifluoromethanesulfonate [Bi(OTf)3] mediated mild electrophilic aromatic formylation utilizing difluoro(phenylsulfanyl)methane (PhSCF2H) as a formylating agent in hexafluoro-2-propanol (HFIP) as a recyclable ionizing solvent has been developed. The active formylating species was generated via C−F bond cleavage and was characterized to be a bis(phenylsulfanyl)methyl cation by experimental and computational 1H and 13C NMR. 2019-08-23T10:49:26Z 2019-08-23T10:49:26Z 2018-08-01 Article Asian Journal of Organic Chemistry. Vol.7, No.8 (2018), 1642-1647 10.1002/ajoc.201800313 21935807 2-s2.0-85051440073 https://repository.li.mahidol.ac.th/handle/123456789/45485 Mahidol University SCOPUS https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85051440073&origin=inward
institution Mahidol University
building Mahidol University Library
continent Asia
country Thailand
Thailand
content_provider Mahidol University Library
collection Mahidol University Institutional Repository
topic Chemistry
spellingShingle Chemistry
Nolan M. Betterley
Sutthichat Kerdphon
Suppisak Chaturonrutsamee
Sopanat Kongsriprapan
Panida Surawatanawong
Darunee Soorukram
Manat Pohmakotr
Pher G. Andersson
Vichai Reutrakul
Chutima Kuhakarn
Bi(OTf)<inf>3</inf> Enabled C-F Bond Cleavage in HFIP: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl)methane
description © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Bismuth(III) trifluoromethanesulfonate [Bi(OTf)3] mediated mild electrophilic aromatic formylation utilizing difluoro(phenylsulfanyl)methane (PhSCF2H) as a formylating agent in hexafluoro-2-propanol (HFIP) as a recyclable ionizing solvent has been developed. The active formylating species was generated via C−F bond cleavage and was characterized to be a bis(phenylsulfanyl)methyl cation by experimental and computational 1H and 13C NMR.
author2 Kasetsart University
author_facet Kasetsart University
Nolan M. Betterley
Sutthichat Kerdphon
Suppisak Chaturonrutsamee
Sopanat Kongsriprapan
Panida Surawatanawong
Darunee Soorukram
Manat Pohmakotr
Pher G. Andersson
Vichai Reutrakul
Chutima Kuhakarn
format Article
author Nolan M. Betterley
Sutthichat Kerdphon
Suppisak Chaturonrutsamee
Sopanat Kongsriprapan
Panida Surawatanawong
Darunee Soorukram
Manat Pohmakotr
Pher G. Andersson
Vichai Reutrakul
Chutima Kuhakarn
author_sort Nolan M. Betterley
title Bi(OTf)<inf>3</inf> Enabled C-F Bond Cleavage in HFIP: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl)methane
title_short Bi(OTf)<inf>3</inf> Enabled C-F Bond Cleavage in HFIP: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl)methane
title_full Bi(OTf)<inf>3</inf> Enabled C-F Bond Cleavage in HFIP: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl)methane
title_fullStr Bi(OTf)<inf>3</inf> Enabled C-F Bond Cleavage in HFIP: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl)methane
title_full_unstemmed Bi(OTf)<inf>3</inf> Enabled C-F Bond Cleavage in HFIP: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl)methane
title_sort bi(otf)<inf>3</inf> enabled c-f bond cleavage in hfip: electrophilic aromatic formylation with difluoro(phenylsulfanyl)methane
publishDate 2019
url https://repository.li.mahidol.ac.th/handle/123456789/45485
_version_ 1763489796339007488

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