Electric Fields in Catalysis: From Enzymes to Molecular Catalysts

Electric Fields in Catalysis: From Enzymes to Molecular Catalysts

Electric fields underlie all reactions and impact reactivity by interacting with the dipoles and net charges of transition states, products, and reactants to modify the free energy landscape. However, they are rarely given deliberate consideration in synthetic design to rationally control reactivity...

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Main Authors: Nadia G. Léonard, Rakia Dhaoui, Teera Chantarojsiri, Jenny Y. Yang
Other Authors: Mahidol University
Format: Review
Published: 2022
Subjects:
Chemical Engineering
Chemistry
Online Access:https://repository.li.mahidol.ac.th/handle/123456789/76506
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Institution: Mahidol University
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spelling th-mahidol.765062022-08-04T15:22:07Z Electric Fields in Catalysis: From Enzymes to Molecular Catalysts Nadia G. Léonard Rakia Dhaoui Teera Chantarojsiri Jenny Y. Yang Mahidol University University of California, Irvine Chemical Engineering Chemistry Electric fields underlie all reactions and impact reactivity by interacting with the dipoles and net charges of transition states, products, and reactants to modify the free energy landscape. However, they are rarely given deliberate consideration in synthetic design to rationally control reactivity. This Perspective discusses the commonalities of electric field effects across multiple platforms, from enzymes to molecular catalysts, and identifies practical challenges to applying them in synthetic molecular systems to mediate reactivity. 2022-08-04T08:18:10Z 2022-08-04T08:18:10Z 2021-09-03 Review ACS Catalysis. Vol.11, No.17 (2021), 10923-10932 10.1021/acscatal.1c02084 21555435 2-s2.0-85114367243 https://repository.li.mahidol.ac.th/handle/123456789/76506 Mahidol University SCOPUS https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85114367243&origin=inward
institution Mahidol University
building Mahidol University Library
continent Asia
country Thailand
Thailand
content_provider Mahidol University Library
collection Mahidol University Institutional Repository
topic Chemical Engineering
Chemistry
spellingShingle Chemical Engineering
Chemistry
Nadia G. Léonard
Rakia Dhaoui
Teera Chantarojsiri
Jenny Y. Yang
Electric Fields in Catalysis: From Enzymes to Molecular Catalysts
description Electric fields underlie all reactions and impact reactivity by interacting with the dipoles and net charges of transition states, products, and reactants to modify the free energy landscape. However, they are rarely given deliberate consideration in synthetic design to rationally control reactivity. This Perspective discusses the commonalities of electric field effects across multiple platforms, from enzymes to molecular catalysts, and identifies practical challenges to applying them in synthetic molecular systems to mediate reactivity.
author2 Mahidol University
author_facet Mahidol University
Nadia G. Léonard
Rakia Dhaoui
Teera Chantarojsiri
Jenny Y. Yang
format Review
author Nadia G. Léonard
Rakia Dhaoui
Teera Chantarojsiri
Jenny Y. Yang
author_sort Nadia G. Léonard
title Electric Fields in Catalysis: From Enzymes to Molecular Catalysts
title_short Electric Fields in Catalysis: From Enzymes to Molecular Catalysts
title_full Electric Fields in Catalysis: From Enzymes to Molecular Catalysts
title_fullStr Electric Fields in Catalysis: From Enzymes to Molecular Catalysts
title_full_unstemmed Electric Fields in Catalysis: From Enzymes to Molecular Catalysts
title_sort electric fields in catalysis: from enzymes to molecular catalysts
publishDate 2022
url https://repository.li.mahidol.ac.th/handle/123456789/76506
_version_ 1763497561555992576

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