Synthesis of 4,5-bis (a,a'-Dibromo-m-XYLYL)-1,3-Dithiole-2-Thione: precursor to the preparation of a cobaltadithiolene complex
The Dimercaptoisotrithione (DMIT) derivative, 4,5-bis(a,a'-dibromo-m-xylyl)- 1,3-dithiole-2-thione, which may act as a precursor for the preparation of cobaltadithiolene complexes, was synthesized. The preparation involved the addition of a base (CsOH-H2) to a solution of 4,5-bis(2'-cyanoe...
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| Main Authors: | , |
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| Format: | text |
| Language: | English |
| Published: |
Animo Repository
2006
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| Subjects: | |
| Online Access: | https://animorepository.dlsu.edu.ph/etd_bachelors/6509 |
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| Institution: | De La Salle University |
| Language: | English |
| Summary: | The Dimercaptoisotrithione (DMIT) derivative, 4,5-bis(a,a'-dibromo-m-xylyl)- 1,3-dithiole-2-thione, which may act as a precursor for the preparation of cobaltadithiolene complexes, was synthesized.
The preparation involved the addition of a base (CsOH-H2) to a solution of 4,5-bis(2'-cyanoethylthio)-1,3-dithiole-2-thione to produce a DMIT salt which was then reacted in situ with a,a'-dibromo-m-xylene. The compound and the by-products were characterized by melting point determination, 1H NMR and IR spectroscopy. |
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